1) sulfonium salt
锍盐
1.
The photoinitiated cationic polymerizations of epoxy resins with different functionality (E51,711,TDE85 and AG80)were investigated in the presence of one diphenyliodonium or two kinds of dialkylphenacylsulfonium salt photoinitators.
对4种不同官能度的环氧树脂在紫外光辐照下用一种二苯基碘钅翁盐或两种二烷基苯甲酰锍盐光引发剂进行阳离子光固化的体系作了系统的研究。
2.
This paper is focused on the alkylation reaction of sulfide with 2-halocarbonyl compounds affording sulfonium salts.
本文研究了α-卤代羰基化物和硫醚进行烷基化生成锍盐的反应。
2) sulfonium salts
锍盐
1.
The results show that Eu(fod)4- is an effective NMR shift reagent for sulfonium salts and 1H NMR spectra of methyl shift varies linearly with 13 C NMR spectra of methyl shift in dimethylphenylsulfonium salts in the pres.
研究了以CDCl_3溶剂,NMR位移试剂Eu(fod)_4~-对所合成锍盐的~1H和~(13)C NMR的影响。
2.
In the presence of silver tetrafluoroborate and 1,2 - dichloroethane (as solvent),the thiophenols and methyl phenyl sulfides react with methyl iodide to form dimethylsulfonium salts at ambient temperatUre.
本文报道了7种新二甲基取代苯基锍盐的合成,以取代苯硫酸或苯硫醚为原料,NgBF4-CH3I为烷基化试剂,1,2-二氯乙烷为溶剂室温实现S-甲基化反应。
3) sulphonium ylide
锍内盐
1.
METHOD 1-(2,4-dichloropheny1)-2-(1-imidazoly1)ethanol, the important intermediate of miconazole, was synthesized by epoxidation of 2,4-dichloropheny1aldehyde with sulphonium ylide and by reacting of 2,4-dichloropheny1oxirane with imidazole.
方法 以 2 ,4 二氯苯甲醛为原料 ,在碱性条件下与锍内盐反应得到的 1 (2 ,4 二氯苯基 )环氧乙烷与咪唑反应得到抗真菌药物咪康唑中间体 1 (2 ,4 二氯苯基 ) 2 (1 咪唑基 )乙醇。
4) Tri sulfonium salt
三锍盐
5) sulphonium salt monomer
锍盐单体
6) Methylsulfonium salts
甲基锍盐
补充资料:锍盐
含四价硫的锍离子R3S+和卤素的化合物。锍盐可由硫醚与活泼卤代烃反应制得:
自从维蒂希反应中成功地利用磷叶立德合成烯烃以后,人们发现由锍盐可以制得硫叶立德:
自从维蒂希反应中成功地利用磷叶立德合成烯烃以后,人们发现由锍盐可以制得硫叶立德:
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条