1) sulfonium salt
锍鎓盐
1.
Two kinds of sulfonium salts as Photo-acid Generator have been successfully synthesized.
成功合成了两种新型锍鎓盐类光生酸剂,其结构经1HNMR和MS分析确认,并对其基本物性及在405、365nm光下乙腈溶液中的分解及产酸性能进行了研究,通过计算得出了分解及产酸量子产率。
2.
Two kinds of sulfonium salts as photo-acid generator possess high thermo-decomposition temperature and good solubility in some organic solvents.
对合成的两种新型锍鎓盐光生酸剂进行了基本物性考察,表明它们有较高的热分解温度和在常用有机溶剂中有较好的溶解性,并考察了其在405、365nm 下乙腈中的分解及产酸性能。
2) sulfonium salt
锍盐
1.
The photoinitiated cationic polymerizations of epoxy resins with different functionality (E51,711,TDE85 and AG80)were investigated in the presence of one diphenyliodonium or two kinds of dialkylphenacylsulfonium salt photoinitators.
对4种不同官能度的环氧树脂在紫外光辐照下用一种二苯基碘钅翁盐或两种二烷基苯甲酰锍盐光引发剂进行阳离子光固化的体系作了系统的研究。
2.
This paper is focused on the alkylation reaction of sulfide with 2-halocarbonyl compounds affording sulfonium salts.
本文研究了α-卤代羰基化物和硫醚进行烷基化生成锍盐的反应。
3) sulfonium salts
锍盐
1.
The results show that Eu(fod)4- is an effective NMR shift reagent for sulfonium salts and 1H NMR spectra of methyl shift varies linearly with 13 C NMR spectra of methyl shift in dimethylphenylsulfonium salts in the pres.
研究了以CDCl_3溶剂,NMR位移试剂Eu(fod)_4~-对所合成锍盐的~1H和~(13)C NMR的影响。
2.
In the presence of silver tetrafluoroborate and 1,2 - dichloroethane (as solvent),the thiophenols and methyl phenyl sulfides react with methyl iodide to form dimethylsulfonium salts at ambient temperatUre.
本文报道了7种新二甲基取代苯基锍盐的合成,以取代苯硫酸或苯硫醚为原料,NgBF4-CH3I为烷基化试剂,1,2-二氯乙烷为溶剂室温实现S-甲基化反应。
4) onium salt
鎓盐
1.
The UV-curable acrylated epoxy prepolymer resin was prepared by reacting E-44 epoxy resin with acrylic acid in the presence of onium salt catalyst.
采用E-44环氧树脂与丙烯酸反应,用鎓盐作催化剂,制备了适于配制竹木基涂饰的紫外光固化的环氧丙烯酸酯预聚物,讨论了催化剂的种类对合成反应的影响。
2.
Triarylsulfonium Salts and diaryiodonium salts are photoinitiator for cationic polymerization as well as photo- acid generator.
二芳基碘鎓盐和三芳基硫鎓盐是阳离子聚合的光引发剂和光敏产酸物,但他们在300nm以上的光吸收很低,限制了对紫外光的利用效率。
5) sulphonium ylide
锍内盐
1.
METHOD 1-(2,4-dichloropheny1)-2-(1-imidazoly1)ethanol, the important intermediate of miconazole, was synthesized by epoxidation of 2,4-dichloropheny1aldehyde with sulphonium ylide and by reacting of 2,4-dichloropheny1oxirane with imidazole.
方法 以 2 ,4 二氯苯甲醛为原料 ,在碱性条件下与锍内盐反应得到的 1 (2 ,4 二氯苯基 )环氧乙烷与咪唑反应得到抗真菌药物咪康唑中间体 1 (2 ,4 二氯苯基 ) 2 (1 咪唑基 )乙醇。
6) Tri sulfonium salt
三锍盐
补充资料:己氟磷酸(1-)(氯苯基)[[(氯苯基)硫代]-苯基]苯基锍盐 己氟磷酸(1-)(氯苯基)[[(氯苯基)硫代]苯基]苯基锍盐
CAS:68156-09-2
分子式:C24H17Cl2S2·F6P
中文名称:己氟磷酸(1-)(氯苯基)[[(氯苯基)硫代]-苯基]苯基锍盐 己氟磷酸(1-)(氯苯基)[[(氯苯基)硫代]苯基]苯基锍盐
英文名称:(Chlorophenyl) (chlorophenylthiophenyl) phenylsulfonium hexafluorophosphate (chlorophenyl)[[(chlorophenyl)thio]phenyl]phenyl-sulfoniu hexafluorophospha
分子式:C24H17Cl2S2·F6P
中文名称:己氟磷酸(1-)(氯苯基)[[(氯苯基)硫代]-苯基]苯基锍盐 己氟磷酸(1-)(氯苯基)[[(氯苯基)硫代]苯基]苯基锍盐
英文名称:(Chlorophenyl) (chlorophenylthiophenyl) phenylsulfonium hexafluorophosphate (chlorophenyl)[[(chlorophenyl)thio]phenyl]phenyl-sulfoniu hexafluorophospha
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条