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1)  oxazaphospholidine
噁唑磷烷
1.
Density functional (BHandH) calculations, using 6-31G** basis set, have been employed to study the reaction mechanism of the enantioselectivity in a chiral 1,3,2-oxazaphospholidine-borane cata- lyzed reduction of acetophenone.
应用密度泛函理论BHandH/6-31G**计算方法研究新型手性非金属催化剂1,3,2-噁唑磷烷-硼烷催化还原苯乙酮的对映选择性反应机理,确定了在反应途径上的反应物、络合物、过渡态,中间体和对映体中间产物。
2)  isoxathion [ai,sɔksə'θaiən]
噁唑磷
3)  oxazolidinones
噁唑烷酮
1.
Synthesis and Antibacterial Activity of(S)-5-Acetamidomethyl-3-[(3-chloro-4-substituted aminomethyl)phenyl]-2-oxazolidinones;
(S)-5-乙酰胺甲基-3-[(3-氯-4-取代胺甲基)苯基]-2-噁唑烷酮的合成及抗菌活性
2.
Linezolid is a new class of oxazolidinones antibacterial agents that has been first used in clinical,it inhibits bacterial protein synthesis by blocking the formation of initiation complex.
利奈唑胺(linezolid)是第一个应用于临床的新型噁唑烷酮类抗生素,通过抑制蛋白起始复合物的形成抑制细菌蛋白质合成,在体内、外对葡萄球菌、链球菌、肠球菌等耐药G+菌有广谱的抗菌作用,其临床疗效已经得到一系列Ⅲ期临床研究证明。
3.
The oxazolidinones are a new class of totally synthetic antibacterials that inhibit protein synthesis via binding to a distinct region of 23S RNA of the 50S ribosomal subunit in prokaryotes.
噁唑烷酮类抗菌剂是一类新型的全合成抗菌药物,作用于细菌蛋白质合成的早期阶段(主要作用靶点是核糖体50S亚基的23S rRNA),表现出高度的抗耐药性革兰氏阳性菌活性,其代表药物吗啉噁酮(linezolid)已上市。
4)  oxazolidinone
噁唑烷酮
1.
Analysis of (4S)-4-benzyl-3-(2′(E)-butenyl)-2-oxazolidinone by nuclear magnetic resonance;
(4S)-4-苄基-3-(2’(E)-丁烯酰基)-2-噁唑烷酮的核磁分析
2.
Studies on synthesis of NCPS supported oxazolidinone chiral auxiliary;
线型聚苯乙烯支载噁唑烷酮手性助剂的合成研究
3.
Preparation of (S)-(+)-4-Phenyl-2-oxazolidinone;
手性4-苯基-2-噁唑烷酮的合成研究
5)  oxazolidine [,ɔksə'zɔlidi:n]
噁唑烷
1.
Dimeric Catechin-oxazolidine Tannage and Histological Modality of Fore-and-aft Leather Shrinkage;
二聚儿茶素-噁唑烷鞣法与革收缩前后的组织形态
2.
Resorcin-oxazolidine Combination Tannage;
间苯二酚与噁唑烷结合鞣法研究
3.
THP-oxazolidine-fish Oil Tanning Leather
THP盐-噁唑烷-鱼油鞣革工艺的研究
6)  oxazaborolidine
噁唑硼烷
1.
The asymmetric reduction of ketosulfone with borane catalyzed by oxazaborolidine is computed by means of the semi-empirical MNDO method.
对噁唑硼烷催化前手性酮砜不对称还原反应进行了半经验MNDO研究。
2.
Asymmetric reduction of prochiral ketones using oxazaborolidines has become one of the standard tools for the synthetic chemist, allowing access to enantiomerically enriched secondary alcohols with excellent enantiomeric excess that may seve as the chiral ligands for enantionselectivity synthesis and highly useful intermediates in the sy.
手性噁唑硼烷催化前手性酮的不对称还原反应已成为合成化学家的重要手段之一,这种方法获得的手性仲醇具有较高的ee 值,它们可作为不对称合成中的手性配体及活性物质、天然产物和药物的手性中间体。
补充资料:噁唑磷
分子式:
CAS号:

性质:纯品为浅黄色液体,沸点160℃(20Pa)。水中溶解度为1.9mg/L,易溶于常用有机溶剂。LD50110mg/kg。20世纪60年代后期开发成功的有机磷杀虫剂,可用二乙氧基硫代磷酰氯与3-羟基-5-苯基噁唑反应制取。对昆虫有触杀、胃毒作用,可用于柑橘、烟草、蔬菜等作物防治卷叶蛾、潜叶蛾、锈壁虱、烟青虫、果树食心虫等害虫。制剂有乳油、可湿性粉剂。

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