1) Rhodium complex
铑络合物
1.
A series of hydroformylation catalysts were prepared by supporting Rhodium complex in the supporters modified by phosphotungstic acid.
将铑络合物担载于磷钨酸改性的载体上制备了一系列新型催化剂。
2.
The rhodium complex of novel chiral aminophosphine ligand 6,6'-dimethoxy-2,2'-bis(diphenylphosphinoamino)-1,1'-biphenyl was found to be an effective catalyst for the asymmetric hydrogenation of enamides with product ee's ranging from 51% to 43% and 100 % conversion.
将新颖的手性胺基膦配体 ,6 ,6’_二甲氧基 - 2 ,2’_双 (二苯胺基膦 ) - 1,1’_连苯的铑络合物应用于烯胺类化合物的不对称催化氢化反应中 ,发现这个铑络合物是一个有效的手性催化剂 ,各种手性胺产物的转化率为10 0 % ,光学选择性 (ee)也达到了 5 1%～ 43% 。
3.
Two new types of polysiloxane bound mixed bidentate metal complexs, poly γ N( β butylsulfide)ethylaminopropylsiloxane rhodium complex and poly γ N( β phenylsulfide) ethylaminopropylsiloxane rhodium complex, have been synthesized.
含硫氮双齿配位基的有机硅聚合物和三氯化铑反应，制备了聚－γ－Ｎ（β－丁硫基）乙基胺丙基硅氧烷铑络合物和聚－γ－Ｎ（β－苯硫基）乙基胺丙基硅氧烷铑络合物。
2) Rhodium-phosphine complex
铑-膦络合物
1.
The co-catalysis effect of a series of cationic surfactants including C16H33N(CH3)2CmH2m+1Br(m = 1, 2, 4, 8, 12, 16 ) and C22H45N(CH3)2CnH2n+1Br(n = 1, 2, 4, 8, 12, 16 ) on long-chain hydroformylation catalyzed by rhodium-phosphine complexes in aqueous/biphasic system has been investigated.
系统研究了阳离子表面活性剂C16H33N(CH3)2CmH2m+1Br(m = 1, 2, 4, 8, 12, 16 )、C22H45N(CH3)2CnH2n+1Br(n = 1, 2, 4, 8, 12, 16 )在水溶性铑-膦络合物催化的水/有机两相长链烯烃氢甲酰化反应中的助催化作用。
4) rhodium precursor
铑膦络合物前体
1.
The hydroformylation of 1 octene based on rhodium complex has been investigatedin terms of rhodium precursor,ligand effect and reaction condition of 5MPa ( p (CO)∶ p (H 2)=1∶1),140℃,the activity order of different rhodium precursors is:Rh(CO)(PPh 3)(acac)>[Rh(CH 3COO) 2] 2>Rh 6(CO) 16 .
从铑膦络合物前体、配体和反应条件等 3个方面考察了端辛烯氢甲酰化反应的性质和规律。
5) carbonyl rhodium complex
羰基铑络合物
6) hydroformylation
[,haidrə,fɔ:mi'leiʃən]
水溶性铑-膦络合物
补充资料：(OC-6-11)-六氯合铑酸钠
CAS：14972-70-4
分子式：Cl6Rh·3Na
中文名称：氯化铑钠；(OC-6-11)-六氯合铑酸钠；氯铑酸钠
英文名称：Rhodium sodium chloride；hexachloro, trisodium, (OC-6-11)-Rhodate；Sodium rhodium chloride；sodium hexachlororhodate hydrate
分子式：Cl6Rh·3Na
中文名称：氯化铑钠；(OC-6-11)-六氯合铑酸钠；氯铑酸钠
英文名称：Rhodium sodium chloride；hexachloro, trisodium, (OC-6-11)-Rhodate；Sodium rhodium chloride；sodium hexachlororhodate hydrate
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条