1) ion-association complex
离子缔合物
1.
The RRS intensity was enhanced greatly when Co(Ⅱ) reacted with PAN to form cation chelate complex which further reacted with SDBS to form an ion-association complex in a pH=9.
0的Tris-HCl缓冲溶液中,Co(Ⅱ)与PAN形成带正电荷的二元阳离子螯合物,进而与阴离子表面活性剂SDBS形成离子缔合物Co(Ⅱ)-PAN-SDBS体系,体系RRS强度增强,并产生相应的共振散射光谱。
2.
4,Raloxifene reacts with Evans blue and forms an ion-association complex.
4的NaAc HCl酸性缓冲介质中,药物雷洛昔芬与依文思蓝作用,形成离子缔合物,在280nm处产生强吸收。
3.
This paper introduced the application of ion-association complex for the Solid-Phase Reflection Spectrophotometry which is used in Silver analysis.
在NH4Ac缓冲溶液(pH=7)中,用活化硅胶吸附Ag(Ⅰ)与邻二氮菲(Phen),溴邻苯三酚红(BPR)形成的深蓝色疏水性离子缔合物,直接进行固相反射测定。
2) Ion-association
离子缔合物
1.
A highly sensitive spectrophotometric method was developed for the determination of trace amounts of Iodine based on the oxidation of I~- to I_3~- by IO_3~- and the further reaction of I_3~- with acridine red to form the ion-association complex [AO][I_3]in dilute phosphoric acid solution.
在磷酸介质中,IO_3~-氧化I~-离子形成I_3~-络阴离子,I_3~-络阴离子进一步与吖啶红(AR)阳离子形成离子缔合物,在聚乙烯醇存在下,溶液清亮。
2.
8 KHC_(8)H_(4)O_(4)-HCl buffer solution, in the presence of gum arabic and polyvinyl alcohol ,IO~-_3 oxidated I~- to produce I~-_3, then I~-_3 reacted with methylene blue to form an ion-association.
8苯二甲酸氢钾 盐酸介质中,有阿拉伯胶和聚乙烯醇存在下,IO-3氧化I-生成I-3,I-3再与亚甲基蓝形成离子缔合物,缔合物的最大吸收波长为525nm,表观摩尔吸光系数ε525=1。
3.
The formation of an ion-association among As-Sb-Mo blue and rhodamine B is well distributed in aqueous solution as a steady system under the existence of polyvinyl alcohol .
在非离子表面活性剂聚乙烯醇存在下,砷锑钼蓝与罗丹明B形成紫红色的离子缔合物,其最大吸收波长λmax=590nm,表观摩尔吸光系数ε=1。
3) ion association complex
离子缔合物
1.
It bases on the fact that in acetic acid medium, Hg2+ ion can catalyze the substitute reaction of CN ligand in [Fe(CN)6]4-by 2,2'-bipyridyl (bipy), and the resultant [Fe(bipy)3]2+ cation can react with FinBr4 anion of tetrabromofluorescein (HFinBr4) to form ion association complex [Fe(bipy)3]2+[(FinBr4)2]2- which can emit phosphorescent signal on filter paper substrate.
[(FinBr4)2]2-离子缔合物可在滤纸固体基质上发射室温磷光,据此建立了[Fe(bipy)3]2+。
4) ionic associate
离子缔合物
1.
Study on flotation separation of cadmium(Ⅱ) by ionic associated system;
离子缔合物体系浮选分离镉(Ⅱ)的研究
5) ion associate
离子缔合物
1.
The method was based on the NFLX can reacted with Zn(SCN)4~2- and formed ion associate deposition, so the content of NFLX can be determined indirectly by FAAS.
诺氟沙星分子中含有弱碱性有机胺结构,可与Zn(SCN)_4~(2-)形成离子缔合物沉淀,将沉淀分离后,用火焰原子吸收光谱法测定沉淀中锌(Ⅱ)的含量,间接测定诺氟沙星的含量。
6) ion molecular association
离子分子缔合物
补充资料:离子缔合配位化合物
分子式:
CAS号:
性质:金属离子与配位体配合生成带电(正或负)配位离子,它再与带异性电荷的离子以静电引力的作用结合成的不带电化合物。可表示为[MLn]-[R]+(+、-号可以互换,可以省略)。如在盐酸(HCl)介质中,金属Fe3+离子与配位体Cl-生成络阴离子FeCl4-,乙醚在此条件下生成带正电荷的阳离子(C2H5)2OH+,它们之间互相缔合生成[FeCl4]-[C2H5OH]+缔合物。离子缔合配位化合物在萃取分离方法中广泛应用。
CAS号:
性质:金属离子与配位体配合生成带电(正或负)配位离子,它再与带异性电荷的离子以静电引力的作用结合成的不带电化合物。可表示为[MLn]-[R]+(+、-号可以互换,可以省略)。如在盐酸(HCl)介质中,金属Fe3+离子与配位体Cl-生成络阴离子FeCl4-,乙醚在此条件下生成带正电荷的阳离子(C2H5)2OH+,它们之间互相缔合生成[FeCl4]-[C2H5OH]+缔合物。离子缔合配位化合物在萃取分离方法中广泛应用。
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