1) Prolinamide
脯氨酰胺
1.
(S)——4-hydroxy-L-Proline was N-protected using phenylmethyoxycarbonyl chloride and reacted with t-Butyldimethylsilyl chloride to give(S)-t-Butyldimethylsilyloxy N-phenylmethyoxycarbonyl-L-Proline 2,Which reacted with 2-amino-1,2-diphenylethanol to give L-Prolinamide 3.
以光学活性反式-4-羟基-L-脯氨酸为原料,用苯甲氧羰酰基保护氨基,叔丁基二甲基,硅基保护羟基,然后与1,2-二苯基-2-氨基乙醇反应得到(S)-4-叔丁基二甲基硅氧基-N-苯甲氧羰酰-L-脯氨酰胺3,催化氢解得到(S)-4-叔丁基二甲基硅氧基-L-脯氨酰胺4。
2.
An enantioselective Aldol reaction was catalyzed by prolinamides synthesized from optically pure binaphthol and H8-NOBIN.
以光活性H8-NOBIN和N-叔丁氧羰基-L-脯氨酸为原料合成了2个脯氨酰胺。
2) D-prolinamide
D-脯氨酰胺
1.
New synthetic route for D-prolinamide;
D-脯氨酰胺的合成新工艺
2.
As an important pyrrolidine derivative, D-Prolinamide shows its excellent asymmetric source potential both in synthesizing chiral Pharmaceuticals and asymmetric reactions, such as CDDP, TRF, Remoxipride and Neuroleptic.
D-脯氨酰胺(D-Prolinamide)作为一种重要的光学活性吡咯衍生物,无论是用作拆分剂和手性试剂,或作为手性中间体合成某些手性药物,其在各种不对称合成反应中都显示出了优良的不对称源性能。
3) L-prolinamide
L-脯氨酰胺
1.
Improved synthesis of L-prolinamide;
L-脯氨酰胺的合成工艺改进
2.
Benzyl 3-formyl-2-hydroxy-3-methyl butanoate(1) was synthesized by L-prolinamide catalyzed asymmetric cross Aldol reaction of benzyl glyoxylate with isobutanal in yield of 93% with 52%e.
乙醛酸苄酯与异丁醛间在L-脯氨酰胺催化下发生不对称交叉羟醛缩合反应,以93%的产率得到e。
4) prolinamide derivative
脯氨酰胺衍生物
5) N-(S)-prolylhydroxylamine
(S)-脯氨酰羟胺
6) N-prolylbenzenesulfonamide
N-磺酰基脯氨酰胺
补充资料：豆脯
1.豆腐。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条