1) 4,4'-bipyridine
4,4′-联吡啶
1.
The crystal structure shows that the title compound consists of one polyoxomatelate(PMo12O403-) with the Keggin structure,two 4,4′-bipyridine cations,two 4,4′-bipyridine molecules and seven water molecules.
标题化合物分子由1个具有Keggin结构的[PMo12O40]3-、2个质子化的4,4′-联吡啶分子、2个未质子化的4,4′-联吡啶分子及7个水分子构成,分子中存在丰富的氢键作用。
2.
Crystallization from a mixed solution of dichloromethane (CH2Cl2) and acetonitrile (CH3CN) containing copper(Ⅰ) tetrafluroborate, 4,4′-bipyridine (4,4′-bipy) and either bis-[2-(diphenylphosphino)phenyl]ether (POP) or triphenylphosphine (PPh3), by diethyl ether (Et2O) vapour diffusion methods yielded [Cu2(4,4′-bipy)(POP)2(CH3CN)2 (C2H5O)2](BF4)2 (1) and [Cu2(4,4′-bipy)(PPh3)4(CH3CN)2](BF4)2 (2).
采用乙醚蒸汽扩散法,由四氟合硼酸四乙腈合铜髣、4,4′-联吡啶、二(2-二苯基膦基)苯基醚或者三苯基膦的反应后的二氯甲烷和乙腈混合溶液中,晶化出[Cu2(4,4′-bipy)(POP)2(CH3CN)2(C2H5O)2](BF4)2(1)和[Cu2(4,4′-bipy)(PPh3)4(CH3CN)2](BF4)2(2)两种配合物。
3.
A new 1D complex {[Cu(L)(4,4′-bpy)]·ClO_4}_n[L=2-((2-hydrox-yethylimino) methyl)phenol,bpy=4,4′-bipyridine]has been prepared.
合成了一个新颖的一维Cu(Ⅱ)配位聚合物{[Cu(L)(4,4′-bpy)]·ClO_4}_n[L=N-(2-羟乙基)水杨醛亚胺,bpy=4,4′-联吡啶]。
2) 4,4'-bipyridine
4,4'-联吡啶
1.
Synthesis and Crystal Structure of Ternary Copper(Ⅱ) Complex Containing N-(2-hydroxybenzyl)-DL-alanine and 4,4′-bipyridine;
Cu(Ⅱ)与N-(2-羟苄基)-DL-丙氨酸、4,4′-联吡啶三元配合物的合成与晶体结构
2.
High Selective Nucleophilic Substitution Reaction of 4,4′-bipyridine Under Solvent-free Conditions;
无溶剂4,4′-联吡啶高选择性亲核取代反应
3.
Theoretical comparative studies of the dihedral angle andtorsional barriers for 4,4′-bipyridine;
4,4′-联吡啶二面角和扭转势垒的理论研究
3) 4,4'-bipyridyl
4,4'-联吡啶
1.
The Cu atom is in a geometry of distorted octahedral built by three oxygen atoms of two bidentate chelate carboxylic groups of the ligand(p-Ab-),one oxygen atom from a H2O molecule,and three nitrogen atoms of the ligand of 4,4′-bipyridyl.
4H2O}n(4,4′-bpy=4,4′-联吡啶,p-Ab-=对氨基苯甲酸根离子),该配合物晶体属单斜晶系,P2(1)/c空间群,晶胞参数:a=1。
4) 4,4-bipyridine
4,4-联吡啶
1.
Synthesis and Crystal Structure of the Complexes formed by Co(Ⅱ)、Cu(Ⅱ) and 4,4 -bipyridine;
4,4 -联吡啶钴(Ⅱ)、铜(Ⅱ)配合物的合成及其晶体结构
2.
NMR and Theoretical Studies on Interactions between Biperoxovanadate and 4,4 -bipyridine;
双过氧钒配合物与4,4 -联吡啶相互作用的NMR和理论研究
3.
Reactions of CuCl_2·2H_2O and Cu(NO_3)_2·3H_2O with 4,4 -bipyridine gave complex 1 and complex 2,respectively, which were characterized by X-ray diffraction and Raman spectroscopy.
采用4,4 -联吡啶与CuCl_2·2H_2O,Cu(NO_3)_2·3H_2O反应合成配合物1和配合物2,并采用XRD、拉曼对配合物1和配合物2进行了表征。
5) 4,4' bipyridinium salts
4,4'-联吡啶盐
6) 4,4'-Dithiodipyridine
4,4'-二硫联吡啶
1.
Study on the Effect of Solution pH Value on Assembling of Gold Nanoparticles on 4,4'-Dithiodipyridine Self-assembled Monolayers by Surface-enhanced Raman Scattering Spectroscopy;
在4,4’-二硫联吡啶在Au表面形成自组装单分子层膜的基础上,采用表面增强拉曼散射光谱(SERS)研究了在不同pH值条件下金纳米粒子在4,4’-二硫联吡啶自组装单分子膜/Au体系表面的组装。
补充资料：4,4′-联吡啶
分子式：
CAS号：
性质：无色或浅黄色结晶，熔点114℃，沸点305℃；能升华，溶于热水、乙醇、氯仿和苯；其N-氧化物熔点180℃，N-N′-二氧化物熔点335℃；用高锰酸钾溶液氧化，得到异尼古丁酸；用钠和乙醇还原，得到4,4′-联哌啶；用作氧化还原指示剂，在还原剂作用下呈蓝色；其二盐酸盐用作除草剂。
CAS号：
性质：无色或浅黄色结晶，熔点114℃，沸点305℃；能升华，溶于热水、乙醇、氯仿和苯；其N-氧化物熔点180℃，N-N′-二氧化物熔点335℃；用高锰酸钾溶液氧化，得到异尼古丁酸；用钠和乙醇还原，得到4,4′-联哌啶；用作氧化还原指示剂，在还原剂作用下呈蓝色；其二盐酸盐用作除草剂。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条