1) amide reduction
酰胺还原
2) Trypanothione reductase
谷胱甘酰亚精胺还原酶
1.
Trypanothione reductase is a member of the family of FAD containing pyridine nucleotide disulfide oxidoreductase and catalyzes the NAD(P)H dependent reduction of trypanothione,N 1,N 8 bis(glutathionyl) spermidine,T(S) 2,a cyclic glutathione analog unique to trypanosomatid parasites.
锥虫谷胱甘酰亚精胺还原酶属黄素氧化还原酶类 ,特异存在于锥体目生物却不存在于宿主体内。
3) reductive acylation
还原酰化
4) reductive amination
还原胺化
1.
This paper reviews the recent progress of all kinds of reductive amination methods and their ap-plications in organic synthesis, particularly emphasis on the introduction to the reductive amination with high efficiency and high selectivity.
综述了近几年来各种还原胺化方法的研究进展及其在合成中的应用,尤其对高效和高选择性的还原胺化进行了重点介绍。
2.
Racemic 5-methoxy-2-(N-propylamino)tetralin was subsequently prepared by a reductive amination reaction using n-propylamine and the racemic mixture successfully resolved to give the chiral compound (-)-5-methoxy-2-(N-propylamino)tetralin, which was finally converted to (-)-5-hydroxy-2-(N-propylamino) tetralin via a demethylation reaction.
以1,6-二甲氧基萘为原料,经Na/C2H5OH还原生成5-甲氧基-2-四氢萘酮,与正丙胺还原胺化生成外消旋化合物2-(N-正丙基氨基)-5-甲氧基四氢化萘,经拆分得到手性的化合物(-)-2-(N-正丙基氨基)-5-甲氧基四氢化萘,再去甲基反应得到化合物(-)-2-(N-正丙基氨基)-5-羟基四氢化萘。
3.
The reductive amination in ionic liquids was researched.
以离子液体为反应介质,对一系列还原胺化反应进行了研究。
6) reduction of imines
亚胺还原
1.
Catalytic enantioselective reduction of imines represents one of the moststraightforward and efficient methods for the preparation of chiral amines, animportant intermediate for the synthesis of natural products and chiral drugs.
文献研究认为，除N-甲酰基外，分子内含有芳香酰胺是能催化亚胺还原的有机小分子路易斯碱催化剂具有较高对映选择性的必要条件，我们研究发现N-甲酰脯氨酸非芳香酰胺类催化剂(包括结构简单的C_2-对称型脯氨酰胺类催化剂)，对N-芳基酮亚胺的还原可获得达86％的对映选择性，远高于同类芳香酰胺催化剂，证明N-甲酰非芳香酰胺类路易斯碱催化剂在亚胺还原中也能得到高的对映选择性。
补充资料：水谷之精
水谷之精 水谷之精 生理学名词。指饮食物经过消化吸收而化生的营养 精华，它是人体生长发育、维持生命活动的物质基础。而来源于饮食水谷，禀受于后天，故又称后天之精。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条