In addition the photoinduced catalytic hydrogen production catalyzed by the light-driven model compounds each containing a H_2TPP photosensitizer,as well as electrochemical properties of some transition metal fullerene complexes,self-assembly organometallic complexes and metallocrown ethers each containing a butterfly Fe_2S_2 core were also discussed in this paper.

This paper introduces the discovery of endohedral metallfullerenes and its significance, as well as the synthesis, purification and characterization methods.

It were introduced that some Addition reaction of carbonyl compounds with allylic metallorganic compounds,and it were discussed by reaction mechanism.

The progess in the research of metallofullerenes about synthesis、extraction and isolation;

The Difference Gd∶C to the Results of Metallofullerenes Formation and MS Study;

Synthesis and Characterization of Water-soluble Metallofullerene Derivatives;

A detailed review on the synthesis extraction, structure and the potential application of metallofullerenes is presented.

It is found that under high temperature and high pressure conditions, the extraction of the metallofullerenes Gd@C 82 with C 5H 9NO is more efficient and more selective.