炔丙基卤,propargylic halide,propargyl halide,在线英语词典,英文翻译,专业英语

1) propargylic halide,propargyl halide

炔丙基卤

2) propinol

炔丙醇

The reaction mechanism, thermodynamic and kinetic behavior of the dipole cycloaddition reaction of benzaldoxime with propinol have been studied by DFT method at B3LYP/6-31G* level.

用密度泛函理论(DFT)方法在B3LYP/6-31G*水平上研究了苯甲醛肟与炔丙醇加成反应的微观机制和热力学、动力学行为。

Z) -3-tri- p -tolystarnyl-1,1-diphenylpropenol was synthesized by the reaction of tri- p -tolytio hydrde with 1,1-diphenylpropinol and characterized by elemental analysis.

利用三（对甲苯基）氢化锡与１，１－二苯基炔丙醇的加成合成了（Ｚ）－３－三（对甲苯基）锡基－１，１－二苯基烯丙醇，通过元素分析、１ＨＮＭＲ、ＩＲ光谱、紫外光谱、ＴＧＡ－ＤＳＣ热分析等对其进行了结构表征和性质研究。

3) prallethrin

炔丙菊酯

4) propargyl alcohol

炔丙醇

From the reactions of camphene with propargyl alcohol,2butyn1ol and 3trimethyl siliconic propargyl alcohol in the presence of 4methylbenzenesulfonic acid,bornyl propargyl ether(2a),bornyl 2butynyl ether (2b) and bornyl 3trimethyl siliconic propargyl ether(2c) are prepared respectively with corresponding yield 74 %,68 % and 63 %.

莰烯在对甲苯磺酸等催化下与炔丙醇、２炔丁醇、３三甲基硅基炔丙醇反应，分别制得冰片基炔丙基醚、冰片基２炔丁基醚和冰片基（３三甲基硅基）炔丙基醚，产率６３％～７４％。

5) propargylation

炔丙基化

Electrophilic additions between propargylic alcohols and acetylacetone were carried out using FeCl3 as a catalyst in 1,2-dichloroethane at refluxing for 8 h under nitrogen atmosphere to obtain propargylation products in yields of 80.

FeCl3催化炔丙醇与乙酰丙酮在1,2-二氯乙烷中发生亲电加成反应得炔丙基化产物——3-炔丙基-2,4-戊二酮,其结构经1H NMR,13C NMR,IR和MS表征。

6) homopropargylic alcohol

高炔丙醇

Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohols were found.

在金属镝的促进下,醛、酮可与炔丙基溴反应,高选择性高产率地得到相应的高炔丙醇,没有发现连二烯醇的存在。

参考词条

炔丙基碘炔丙基脲二炔丙基联炔丙基炔丙醛二炔丙基芴高炔丙基醇炔丙基硒醚单颗粒锆石U-Pb测年防洪门

补充资料：反-1-丙炔基-4-丙基环己基苯

CAS: 88074-91-3

中文名称: 反-1-丙炔基-4-丙基环己基苯

英文名称: 1-propynyl, 4-propylcyclohexyl, trans-Benzene
Benzene,1-propynyl,4-propylcyclohexyl,trans-

说明：补充资料仅用于学习参考，请勿用于其它任何用途。

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1) propargylic halide,propargyl halide 炔丙基卤 2) propinol 炔丙醇 1. The reaction mechanism, thermodynamic and kinetic behavior of the dipole cycloaddition reaction of benzaldoxime with propinol have been studied by DFT method at B3LYP/6-31G* level. 用密度泛函理论(DFT)方法在B3LYP/6-31G水平上研究了苯甲醛肟与炔丙醇加成反应的微观机制和热力学、动力学行为。 2. Z) -3-tri- p -tolystarnyl-1,1-diphenylpropenol was synthesized by the reaction of tri- p -tolytio hydrde with 1,1-diphenylpropinol and characterized by elemental analysis. 利用三（对甲苯基）氢化锡与１，１－二苯基炔丙醇的加成合成了（Ｚ）－３－三（对甲苯基）锡基－１，１－二苯基烯丙醇，通过元素分析、１ＨＮＭＲ、ＩＲ光谱、紫外光谱、ＴＧＡ－ＤＳＣ热分析等对其进行了结构表征和性质研究。 3) prallethrin 炔丙菊酯 4) propargyl alcohol 炔丙醇 1. From the reactions of camphene with propargyl alcohol,2butyn1ol and 3trimethyl siliconic propargyl alcohol in the presence of 4methylbenzenesulfonic acid,bornyl propargyl ether(2a),bornyl 2butynyl ether (2b) and bornyl 3trimethyl siliconic propargyl ether(2c) are prepared respectively with corresponding yield 74 %,68 % and 63 %. 莰烯在对甲苯磺酸等催化下与炔丙醇、２炔丁醇、３三甲基硅基炔丙醇反应，分别制得冰片基炔丙基醚、冰片基２炔丁基醚和冰片基（３三甲基硅基）炔丙基醚，产率６３％～７４％。 5) propargylation 炔丙基化 1. Electrophilic additions between propargylic alcohols and acetylacetone were carried out using FeCl3 as a catalyst in 1,2-dichloroethane at refluxing for 8 h under nitrogen atmosphere to obtain propargylation products in yields of 80. FeCl3催化炔丙醇与乙酰丙酮在1,2-二氯乙烷中发生亲电加成反应得炔丙基化产物——3-炔丙基-2,4-戊二酮,其结构经1H NMR,13C NMR,IR和MS表征。 6) homopropargylic alcohol 高炔丙醇 1. Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohols were found. 在金属镝的促进下,醛、酮可与炔丙基溴反应,高选择性高产率地得到相应的高炔丙醇,没有发现连二烯醇的存在。参考词条炔丙基碘炔丙基脲二炔丙基联炔丙基炔丙醛二炔丙基芴高炔丙基醇炔丙基硒醚单颗粒锆石U-Pb测年防洪门补充资料：反-1-丙炔基-4-丙基环己基苯 CAS: 88074-91-3 中文名称: 反-1-丙炔基-4-丙基环己基苯英文名称: 1-propynyl, 4-propylcyclohexyl, trans-Benzene Benzene,1-propynyl,4-propylcyclohexyl,trans- 说明：*补充资料仅用于学习参考，请勿用于其它任何用途。
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