1) lithium, ( beta-4)-aluminate tetrahydro-
四氢化铝锂
2) lithium aluminium hydride
四氢化锂铝
3) tetrahydralli
四氢铝锂
1.
A new polymer with structure of 1,4-diethynylbenzene and phenylsinylene in the main chain was synthesized by taking 1,4-diacetylenebenzene and phenyl silane(PhSiH_3) as material,tetrahydralli as catalyst,by dehydrogenation between C C H in 1,4-diacetylenebenzene and Si H in phenyl silane under 120 ℃.
以14-二乙炔基苯和苯基硅烷(PhSiH3)为原料、四氢铝锂为催化剂,在120℃下,通过14-二乙炔基苯中的炔氢和苯基硅烷中的硅氢间的脱氢反应,合成了主链带苯炔基和苯基硅亚甲基的新型聚合物;采用IR和1HNMR表征了其结构,并对其性能及固化反应机理进行了研究。
4) Lithium aluminum hydride
四氢锂铝
5) lithium aluminium hydride
氢化铝锂
1.
According to the strong reducibility of lithium aluminium hydride and asymmetric selectivity of binaphthol,the authors reduce camphor into D-borneol by using D-binaphthol modified lithium aluminium hydride as chiral reagent.
根据氢化铝锂的强还原性和联萘酚的不对称选择性,用右旋联萘酚改性过的氢化铝锂为手性试剂,把樟脑还原成右旋龙脑。
2.
0]nonane (C14H16N2O2)by the reduction of lithium aluminium hydride.
采用氢化铝锂还原8-苄基-7,9-二氧代-2,8-二氮杂双环[4。
3.
In this method,2,6-Difluorobenzamide used for the raw material,lithium aluminium hydride used for the reducing agent.
该方法以2,6-二氟苯甲酰胺为原料用氢化铝锂还原,该方法反应条件温和、操作以及分离简便,并且通过实验得出该反应的最佳反应条件,目标化合物通过红外、核磁等分析手段进行了确认。
6) lithium aluminum hydride
氢化铝锂
1.
A novel reaction of α,β-unsaturated esters and ketones with lithium aluminum hydride in dry tetrahydrofuran solution at 0 ℃ affords, in addition to saturated and unsaturated alcohols, the corresponding 1,3-diols in moderate yield.
在 0℃下 ,以四氢呋喃为溶剂 ,用氢化铝锂还原α ,β 不饱和酯和酮 ,除得到正常的还原产物一醇外 ,还以适中的产率方便地得到 1,3 二醇 ,该反应原料易得 ,操作简单 ,有望应用于合成含有 1,3 二醇骨架结构的天然产
2.
A chiral reagent prepared by (1S, 2R) 1 dibutylamino 2 indanol (R*OH) and lithium aluminum hydride was first applied to the asymmetric reduction of acetophenone.
(1S,2R)-1-二丁氨基-1,2-二氢-2-茚醇(ROH)与氢化铝锂形成的手性试剂首次用于苯乙酮的不对称还原研究。
3.
A novel method was developed and carefully studied for the synthesis of polyoxygenated cyclohexene-yl-methanol from shikimic acid by means of esterification with methanol,followed by protection by DMP and TBDMSCl and reduction by mixed THF solution of lithium aluminum hydride and aluminum chloride.
以莽草酸为原料,与甲醇成酯,然后丙酮叉保护顺式的邻二羟基,叔丁基二甲硅氯保护另一个羟基,最后用氢化铝锂和三氯化铝还原,得到标题化合物,其结构经IR1、HNMR、HR-MS确证,总产率86。
补充资料:四氢化铝锂
CAS:16653-65-3
分子式:AlH4·Li
分子质量:37.95
熔点:125℃
中文名称:氢化铝锂;四氢化铝锂;(T-4)-四氢铝酸锂
英文名称:tetrahydro-, lithium, (T-4)-Aluminate;tetrahydro-aluminate lithium;tetrahydro-aluminate lithium;lithium, ( beta-4)-aluminate tetrahydro-;aluminum lithium hydride;hydrure de lithium et d'aluminium
分子式:AlH4·Li
分子质量:37.95
熔点:125℃
中文名称:氢化铝锂;四氢化铝锂;(T-4)-四氢铝酸锂
英文名称:tetrahydro-, lithium, (T-4)-Aluminate;tetrahydro-aluminate lithium;tetrahydro-aluminate lithium;lithium, ( beta-4)-aluminate tetrahydro-;aluminum lithium hydride;hydrure de lithium et d'aluminium
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