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1)  ion pair polymerization
离子对聚合
2)  cationic polymerization
正离子聚合,阳离子聚合
3)  anionic polymerization
负离子聚合,阴离子聚合
4)  cationic polymerization
阳离子聚合
1.
Reaction order of TiCl 4 in cationic polymerization of isobutylene in the presence of the reagents containing nitrogen;
含氮试剂调节异丁烯阳离子聚合中TiCl_4的反应级数
2.
Study on mechanism of third component in cationic polymerization system of isobutylene;
第三组分在异丁烯阳离子聚合体系中的作用机理研究
3.
Then using this polymer as grafting agent,a novel branched polymer that each arm of star-shaped PS-b-PI contained several polyisobutylene was prepared via cationic polymerization.
然后以此星形大分子作为接枝剂,通过阳离子聚合,合成了一种在每个星形大分子的臂上接枝几个聚异丁烯的新型支化聚合物,并对其进行了GPC、1H-NMR、FT-IR等分析表征,讨论了不同的加料顺序对其的影响,1H-NMR结果表明其接枝效率达80%左右。
5)  anionic polymerization
阴离子聚合
1.
Numerical simulation of reactive extrusion processes for anionic polymerization of styrene;
苯乙烯阴离子聚合反应挤出过程的数值模拟
2.
Chemical calorific effect during reactive extrusion process for anionic polymerization;
阴离子聚合反应挤出过程的化学热效应
3.
Polar additives in anionic polymerization;
阴离子聚合反应中的极性调节剂
6)  anion polymerization
阴离子聚合
1.
Octamethylcyclotetrasiloxane(D4)and N-(β-aminoethyl)-γ-aminopropylmethyldimethoxysilane(KH-792) were chosen to synthesize aminopolysiloxane by bulk anion polymerization,with KOH as catalyst,hexamethyldisiloxane(MM)used as end capping agent,and dimethyl sulfoxide(DMSO) utilized as accelerating agent.
以八甲基环四硅氧烷(D4)和N-β-氨乙基-γ氨丙基甲基二甲氧硅烷(KH-792)为原料,用KOH作为催化剂,六甲基二硅氧烷(MM)为封端剂,二甲基亚砜(DMSO)为促进剂,采用本体阴离子聚合法合成了氨基封端的聚硅氧烷,对其结构用红外光谱进行了表征。
2.
We synthesized (SI)_4Si star-type block copolymer with styrene,isoprene and silicon tetrachloride as raw materials,tetrahydrofuran as molecular weight regulator,cyclohexane as solvent,and n-BuLi or naphthalene lithium as initiating agent by anion polymerization method with three steps.
采用阴离子聚合法,以苯乙烯、异戊二烯、四氯化硅为原料,以四氢呋喃(THF)为分子量调节剂,正丁基锂或萘锂为引发剂,环己烷为溶剂,分3步加料,合成(SI)4Si星型嵌段共聚物。
3.
Synthesis methods of PFPE are mainly anion polymerization of perfluoro-epoxide and photo-initiated oxidation of perfluoro-olefine.
其合成方法主要有全氟环氧化物的阴离子聚合法和全氟烯烃直接光氧化法2种。
补充资料:离子对聚合
分子式:
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性质:用碱金属或碱土金属阳离子与聚合物分子链的端基或侧基上的羧基负离子发生中和反应,称为离子对聚合。这种聚合依靠静电吸力形成离子键,较高温度时结合减弱呈现热塑性。

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