1) soap-free emulsion polymerization
无皂乳液聚合法
1.
Polyvinyl alcohol(PVA)grafted cationic polyacrylate resin was prepared by soap-free emulsion polymerization of styrene,butyl acrylate,methacrylic acid,and methacryloxyethyl trimethylammonium chloride,using potassium persulfate as initiator,isopropanol as cosolvent,PVA as dispersing agent and glyoxal as crosslinker.
在引发剂过硫酸钾和少量助溶剂异丙醇的作用下,以聚乙烯醇(PVA)为分散剂,乙二醛为交联剂,苯乙烯、丙烯酸丁酯、甲基丙烯酸和甲基丙烯酰氧乙基三甲基氯化铵为主要单体,采用无皂乳液聚合法制备了出PVA接枝改性阳离子丙烯酸树脂,并用该树脂制备了一系列乳胶膜。
2) Emulsifier-free emulsion polymerization
无皂乳液聚合法
1.
Various polymerization methods to prepare functional polyacrylamide microspheres were discussed,especially two main methods: dispersion polymerization and emulsifier-free emulsion polymerization.
介绍了功能性聚丙烯酰胺类微球的各种制备方法,主要为分散聚合法和无皂乳液聚合法。
3) soap-free emulsion polymerization
无皂乳液聚合
1.
Nano silica was modified by soap-free emulsion polymerization using methacrylic acid (MA) and acrylic acid (AA)as monomer;
MA/AA无皂乳液聚合改性纳米SiO_2
2.
Preparation of fluorocarbon polymer emulsion by the method of soap-free emulsion polymerization;
无皂乳液聚合法制备氟碳聚合物乳液
3.
Research on reaction mechanism and preparation methods of soap-free emulsion polymerization;
无皂乳液聚合反应机理和制备方法的研究进展
4) emulsifier-free emulsion polymerization
无皂乳液聚合
1.
Novel application and technical progress of emulsifier-free emulsion polymerization;
无皂乳液聚合技术及应用研究进展
2.
The research progress on ultrasonically initiated emulsifier-free emulsion polymerization;
超声波辐照无皂乳液聚合研究进展
3.
Preparation of monodisperse micron-size polystyrene particles by emulsifier-free emulsion polymerization;
无皂乳液聚合制备亚微米级单分散聚苯乙烯微球
5) soapless emulsion polymerization
无皂乳液聚合
1.
By means of a soapless emulsion polymerization method, the polymerization of styrene(St) and butyl acrylate (BA) on the surface of nano CaCO 3 in an aqueous phase was carried out.
将苯乙烯 (St)、丙烯酸丁酯 (BA)在纳米碳酸钙粒子存在下的水相悬浮液中进行无皂乳液聚合 ,制备纳米碳酸钙聚合物复合微粒。
2.
By means of soapless emulsion polymerization method, the polymerization of methyl methacrylate (MMA) at the suface of titanium dioxide (TiO2) particles has been carried out.
本文采用无皂乳液聚合法,使甲基丙烯酸甲酯(MMA)在TiO2粒子表面进行聚合,得到了以TiO2粒子为核,聚甲基丙烯酸甲酯(PMMA)为壳的复合粒子,TiO2粒子表面由此得到改性研究了TiO2表面聚合物成膜的条件,用TEM证实了表面聚合物膜的存在,运用IR和DTA对复合粒子进行了表征,并利用Zeta电位,接触角的测定及分散性试验对改性前后TiO2的表面性质进行了研究。
6) emulsifier free emulsion polymerization
无皂乳液聚合
1.
A series cationic emulsion copolymers based on methyl acrylate(MA),styrene(St),acrylamide(AM) and trimethylaminoethylmethacrylate chloride(TMC) were synthesixzed by mean of emulsifier free emulsion polymerization.
以丙烯酸甲酯(MA)、苯乙烯(St)、丙烯酰胺(AM)、甲基丙烯酰氧乙基三甲基氯化铵(MTA)为原料,采用无皂乳液聚合法合成出了一系列阳离子共聚物(PMAA)乳液,将PMAA乳液加到草浆中,通过对纸张的环压强度、耐破度和撕裂度等的测定,发现当乳液的用量为0。
2.
The physicol chemical properties of P (styrene buthyl acrylate sodium undecylenate) electrolyte microsphere synthesised by emulsifier free emulsion polymerization were studied under the condition of ionic environment.
对由无皂乳液聚合法合成的苯乙烯 丙烯酸丁酯 十一烯酸钠高分子电解质 [P (St BA UA Na+) ]胶乳微球在离子介质中的物理化学行为进行了讨论。
3.
In this article, monomers allylglycerdyl ether sulfosalt (AGES) and methacrylic acid or acrylic acid were used in the MMA/BA emulsifier free emulsion polymerization system.
烯烃基甘油醚磺酸盐 ( AGES)与甲基丙烯酸 ( MAA)或丙烯酸 ( AA)用于甲基丙烯酸甲酯 ( MMA) /丙烯酸丁酯 ( BA)无皂乳液聚合体系 。
补充资料:无皂乳液聚合
分子式:
CAS号:
性质:即无表面活性剂参与的乳液聚合。无皂乳液聚合得到的胶乳的主要特点是不靠乳化剂起稳定作用,而是靠所得聚合物主链上引入的具有极性的共聚单体(如丙烯酸、醋酸乙烯等)的作用。有时称某些主链上引入的稳定胶乳作用的极性共聚单体为可聚合型的乳化剂(polymerizable surfactant),如乙烯基苯磺酸盐等。与通常的乳液聚合产品相比,无皂乳液聚合产品杂质含量低。
CAS号:
性质:即无表面活性剂参与的乳液聚合。无皂乳液聚合得到的胶乳的主要特点是不靠乳化剂起稳定作用,而是靠所得聚合物主链上引入的具有极性的共聚单体(如丙烯酸、醋酸乙烯等)的作用。有时称某些主链上引入的稳定胶乳作用的极性共聚单体为可聚合型的乳化剂(polymerizable surfactant),如乙烯基苯磺酸盐等。与通常的乳液聚合产品相比,无皂乳液聚合产品杂质含量低。
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