1) monophosphine ligand
单膦配体
1.
Yan shiyan (State Key Laboratory of OXO Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Lanzhou 730000) The double carbonylation reaction of C 6H 5CH 2Cl has been studied using Pd complexes with four new monophosphine ligands as homogeneous catalyst.
利用4种新型单膦配体与钯形成的络合物作为均相催化剂,研究了氯苄双羰基化生成苯基丙酮酸甲酯的催化反应;考察了反应温度、CO压力和Pd/PhCH2Cl(mol比,下同)的影响。
2) phosphine ligands
膦配体
1.
Novel Phosphine Ligands with Cobaltocenium Backbone: Synthesis and Application in Suzuki Coupling Reaction in Ionic Liquids;
二茂钴阳离子膦配体的合成与表征及其在离子液体中催化Suzuki反应研究
2.
In this paper′s work, amphoteric water-soluble chiral phosphine ligands bearing amino acid groups based PPM and amphoteric water-soluble ligands bearing amino acid groups based triphenylphosphine were first designed.
在本论文工作中,设计了两类新型的水溶性膦配体,基于PPM的氨基酸型两性水溶性手性膦配体和基于三苯基膦的氨基酸型两性水溶性膦配体。
3) Diphosphine ligand
双膦配体
1.
This thesis focused mainly on the designing and synthesis of a series of chiral diphosphine ligands with biphenyl backbone and their application in the asymmetric hydrogenation of acetophenon.
本文致力于联苯类手性双膦配体的设计合成,对该类配体三种合成路线进行了考察,通过对文献方法的改进,合成了4个手性双膦配体及11个新的Ru(Ⅱ)-双膦-二胺配合物,并对Ru(Ⅱ)络合物在苯乙酮不对称加氢反应中的催化性能进行了初步考察。
4) phosphine ligand
膦配体
1.
In this paper, phosphine ligand {P[C_6H_5-O(CH_2CH_2O)_nH]_3}was used in therrnoregulatedPEG biphasic system.
本论文把含聚乙氧基链的膦配体PETPP{P[C_6H_5-O(CH_2CH_2O)_nH]_3}用于温控PEG两相催化体系,并分别考察了Rh/PETPP络合物催化剂对1-辛烯、环己烯、二聚异丁烯的氢甲酰化反应的催化活性及催化剂分离回收效果。
2.
It has been reported that some of gold(I) complexes with phosphine ligands show liquid crystalline properties, or nonlinear optical (NLO) behavior, or rich luminescence properties, or photoluminescence properties, etc.
近年来,发现一些含膦配体的炔金配合物表现出液晶性质、非线性光学性质(NLO)、发光性质和光致发光性等。
5) phosphorous ligand
膦配体
1.
Study on application of asymmetric synthesis by chiral phosphorous ligand catalyst;
手性膦配体催化剂在不对称合成中的应用研究
2.
Study on application of asymmetric hydrogenation by chiral phosphorous ligand catalyst;
手性膦配体催化剂在不对称氢化中的应用研究
3.
Double carbonylation reaction of C_6H_5CH_2Cl has been studied using Pd complexes with phosphorous ligands as catalyst.
文章研究了用把单膦配体络合物催化氯苄双羰基化反应生成苯基丙酮酸甲酯的催化反应。
6) Phosphine
[英]['fɔsfi:n] [美]['fɑsfin]
膦配体
1.
Synthesis of New Triarylphosphine Ligands and Their Application in Hydroformylation of Styrene and Hydrogenation of Ketone;
新型膦配体的合成及其在烯烃氢甲酰化和酮类催化加氢反应中的应用研究
2.
A vast number of mono-, bi- and poly-dentate phosphine ligands have been successfully applied in asymmetric catalysis.
手性膦配体的合成及其在不对称催化反应中的应用一直是不对称有机合成和催化研究中非常重要的研究领域 ,大量的单齿、双齿和多齿膦配体被合成出来并成功地应用于不对称催化研究 。
3.
ecent progress is reviewed in synthesis of water soluble phosphine and transition metal complex catalysts as well as their applicanon to catalytic reactions in the aqueous/organic solvent system.
综述了水溶性膦配体的合成,以及水溶性过渡金属络合物催化剂在水/有机两相反应体系中催化剂反应的近期进展。
补充资料:单齿配位体
分子式:
CAS号:
性质:含有一个配位原子与中心离子形成配位键的经典配位体,如氨、卤素离子等。这些配体的配位原子如具有几对孤电子时,也可能键合两个或两个以上中心原子生成多核配位化合物。
CAS号:
性质:含有一个配位原子与中心离子形成配位键的经典配位体,如氨、卤素离子等。这些配体的配位原子如具有几对孤电子时,也可能键合两个或两个以上中心原子生成多核配位化合物。
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参考词条