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1)  phosphorus ligand
有机膦配体
1.
A theoretical study on electronic and steric effects of phosphorus ligands in homogeneous catalysts;
氢甲酰化反应过渡金属络合催化剂有机膦配体调变效应的理论研究
2)  organic ligands
有机配体
3)  organic ligand
有机配体
1.
Effects of organic ligands on accumulation and fractionation of rare earth elements REEs in wheat;
有机配体对稀土元素在小麦体内积累和分异的影响
2.
Cadmium chloride and sodium sulfide were employed as raw materials to prepare hydroxyl coated and size tunable CdS nanocrystal in the presence of 2-mercaptoethanol(ME) as organic ligand.
以氯化镉和硫化钠为原料,2-巯基乙醇(ME)为有机配体,成功制备了粒径可控的、表面富有羟基的CdS纳米晶。
3.
dpV(Ox)) and several organic ligands in solutions were studied by 1H, 13C, and 51 V NMR spectroscopies and electrospray ionization mass spectrometry under the condition of nearly physiological pH value.
应用~1H,~(13)C和~(51)V多核NMR技术和电喷雾质谱等谱学手段研究草酸双过氧钒配合物与吡啶、4-甲基咪唑、咪唑等有机配体的相互作用。
4)  phosphine ligands
膦配体
1.
Novel Phosphine Ligands with Cobaltocenium Backbone: Synthesis and Application in Suzuki Coupling Reaction in Ionic Liquids;
二茂钴阳离子膦配体的合成与表征及其在离子液体中催化Suzuki反应研究
2.
In this paper′s work, amphoteric water-soluble chiral phosphine ligands bearing amino acid groups based PPM and amphoteric water-soluble ligands bearing amino acid groups based triphenylphosphine were first designed.
在本论文工作中,设计了两类新型的水溶性膦配体,基于PPM的氨基酸型两性水溶性手性膦配体和基于三苯基膦的氨基酸型两性水溶性膦配体。
5)  Diphosphine ligand
双膦配体
1.
This thesis focused mainly on the designing and synthesis of a series of chiral diphosphine ligands with biphenyl backbone and their application in the asymmetric hydrogenation of acetophenon.
本文致力于联苯类手性双膦配体的设计合成,对该类配体三种合成路线进行了考察,通过对文献方法的改进,合成了4个手性双膦配体及11个新的Ru(Ⅱ)-双膦-二胺配合物,并对Ru(Ⅱ)络合物在苯乙酮不对称加氢反应中的催化性能进行了初步考察。
6)  phosphine ligand
膦配体
1.
In this paper, phosphine ligand {P[C_6H_5-O(CH_2CH_2O)_nH]_3}was used in therrnoregulatedPEG biphasic system.
本论文把含聚乙氧基链的膦配体PETPP{P[C_6H_5-O(CH_2CH_2O)_nH]_3}用于温控PEG两相催化体系,并分别考察了Rh/PETPP络合物催化剂对1-辛烯、环己烯、二聚异丁烯的氢甲酰化反应的催化活性及催化剂分离回收效果。
2.
It has been reported that some of gold(I) complexes with phosphine ligands show liquid crystalline properties, or nonlinear optical (NLO) behavior, or rich luminescence properties, or photoluminescence properties, etc.
近年来,发现一些含膦配体的炔金配合物表现出液晶性质、非线性光学性质(NLO)、发光性质和光致发光性等。
补充资料:异配位体配位化合物
分子式:
CAS号:

性质:又称异配位体配位化合物。中心离子同时与两种以上不同配体共存于配位内界所组成的单核或多核配位化合物。例如,三氯·氨合铂(II)酸钾和(2)铜(II)-吡啶(py)-水杨酸(sal)配位化合物。在溶液中混配配位化合物的形成是普遍现象。与单一型配位化合物比较,它加强了中心体的化学个性(如易满足高配位数、增强不稳价态稳定性、光学性质改变等),也加强了配体的反应活性和协同萃取效应。在湿法冶金、电化学、分析化学、药物化学、环境化学、生物无机化学和材料化学等方面有着重要作用。

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