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1)  AlCl3 ·6H2 O
三氯化铝(AlCl3·6H2O)
2)  aluminum chloride
三氯化铝
1.
Chloroxylenol was prepared from 3,5-xylenol and chlorine by using aluminum chloride as catalyst.
以间二甲酚和氯气为原料,在三氯化铝的催化下合成了对氯间二甲酚,最佳工艺条件为:四氯化碳70 mL,60℃下通氯反应90 m in,收率可以达61。
2.
Benzoylacrylic acid was obtained by reacting maleic anhydride with benzene via Friedel-Crafts reaction, in the presence of anhydrous aluminum chloride.
顺丁烯二酸酐与苯在三氯化铝的存在下,经傅-克反应生成苯甲酰丙烯酸,在强酸性水介质中,若温度高于35℃,则部分发生与水的加成反应生成苯甲酰乳酸。
3.
A new method of synthesis of N,N-dimethoxyloneethyl aniline was reported by using anhydrous aluminum chloride, aniline, and methacrylate at lower temperature, the conversion,the yield,and the purity was over 95,91,96 respectively.
报道了用无水三氯化铝作催化剂在低温下将苯胺和丙烯酸甲酯转化为N ,N -二甲氧基羰基乙基苯胺的新方法 ,其反应转化率达 95 %以上 ,产品收率高于 91% ,纯度高于96 % 。
3)  aluminium chloride
三氯化铝
1.
The optimum technological factors were studied on the synthesis of 1, 2 - diphenylethane with the reaction of benzene with 1, 2 - dichloroethane catalyzed by anhydrous aluminium chloride.
研究了三氯化铝催化下,1,2-二氯乙烷和苯反应合成1,2-二苯乙烷的最佳工艺条件,结果表明,当苯:二氯乙烷:三氯化铝=10:1:0。
4)  aluminium trichloride
三氯化铝
1.
A new process has been developed to synthesize 2 chloro 2′,4′ difluorophenethyl keton from benzene m difluoride and chloro acetic chloride by catalysis of aluminium trichloride, the optimum reaction conditions have been found by orthogonal experimental design, the production rate was over 90%.
以无水三氯化铝作催化剂 ,间二氟苯与氯乙酰氯反应合成 2 -氯 - 2′,4′-二氟苯乙酮。
2.
Solid acid alchlor catalyst was prepared from anhydrous aluminium trichloride through liquid solid solvent method,with pretreated bentonite as support.
以无水三氯化铝为原料 ,并以处理过的膨润土为载体 ,采用液固溶剂法制备固体酸催化剂。
3.
Then the prepared ester is used to synthesize 1,1-cyclopropanedimethanol through reduction with potassium borohydride and aluminium trichloride.
以丙二酸二乙酯为原料,经C-烃化、还原2步得到1,1-环丙二甲醇,其中在C-烃化反应中,用聚乙二醇(PEG)400作为相转移催化剂催化,碳酸钾作用下,与1,2-二氯乙烷反应得到1,1-环丙烷二甲酸二乙酯;在还原反应中,用硼氢化钾还原,在三氯化铝催化下将1,1-环丙烷二甲酸二乙酯还原得到1,1-环丙二甲醇,2步反应总收率50%~55%。
5)  AlCl_3
三氯化铝
1.
A new route of synthesizing N-β-cyanoethyl aniline, using Aniline and Acrylonitrile as raw materials and catalyzed by AlCl_3 in low temperature, is introduced.
探讨一种用三氯化铝作催化剂 ,在低温下将苯胺和丙烯腈合成为N - β -氰乙基苯胺的新工艺 ,反应收率达96 % ,纯度高于 96 % 。
2.
N-cyanotype ethyl aniline was syrithesized from aniline and acrylonitrile in water at relative low temperature in the presence of AlCl_3 as a catalyst.
报导了以三氯化铝为催化剂、低温条件下合成N-氰乙基苯胺的新工艺。
6)  aluminum trichloride
三氯化铝
1.
Protective effects of glycosides of cistanche on behaviors and memory impairment mice induced by aluminum trichloride;
肉苁蓉总苷对三氯化铝致小鼠学习记忆障碍的保护作用
2.
Alzheimer-like pathological changes of mice induced by D-galactose and aluminum trichloride;
D-半乳糖和三氯化铝诱导小鼠产生类阿尔茨海默病变
3.
The results showed that a better EPDM-g-PS was obtained by using aluminum trichloride as catalyst;the formation of EPDM-g-PS copolymer made the melt mass flow rate of PS/EPDM blend and the glass transition temperature of PS phase decrease,the bonding force on the interf.
结果表明,选择三氯化铝作为PS和EPDM大分子间形成接枝共聚物EPDM-g-PS的催化剂时效果较好;EPDM-g-PS的生成使PS/EPDM共混物的熔体质量流动速率和PS相的玻璃化温度下降,增大了PS和EPDM两相的界面结合力,从而提高了共混物的性能;当PS/EPDM共混比为60/40、三氯化铝用量为3份、混炼温度为140℃、混炼时间为5 min时,共混物综合性能较好。
补充资料:三氯化铝(六水)
CAS:7784-13-6
分子式:AlCl3H12O6
分子质量:241.43
中文名称:六水合氯化铝;三氯化铝(六水);氯化铝,六水
英文名称:Aluminium chloride, hexahydrate;aluminum chloride, hexahydrate;aluminium chloride hexahydrate;aluminum chloride hexahydrate;aluminum chloride hydrated;aluminum chloride, hydrous
性状描述:淡黄色粉末或颗粒结晶,六方晶体系.三氯化铝相对密度425,2.44,熔点194℃(2.5大气压)。暴露在空气中产生刺激性烟雾,至178℃即升华;有强烈腐蚀性,遇水分解产生氯化氢气体,并产生热量,反应剧烈时甚至爆炸。三氯化铝易溶于多种有机溶剂如氯仿;四氯化碳;无水酒精和乙醚。
生产方法:主要原料及规格:铝锭(Al)≥95% 液氯(Cl2)≥99.5%化学反应式:2Al + 3Cl2 → 2AlCl3
用途:三氯化铝多用作有机合成的催化剂,广泛用于石油裂解,合成染料,合成橡胶,合成树脂,合成洗涤剂;医药;香料;农药等。
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