1) 5-amino-1,10-phenanthroline
5-氨基-1,10-邻菲罗啉
1.
With recovered and regenerated 5% Pd/C as catalyst and hydrazine hydrate as reductant, 5-amino-1,10-phenanthroline was synthesized by reduction of 5-ntiro-1,10-phenanthroline which was synthesized from phenanthroline by nitration.
由1,10-邻菲罗啉经硝化制得5-硝基-1,10-邻菲罗啉,再经还原合成了5-氨基-1,10-邻菲罗啉。
2) 5-nitro-1,10-phenanthroline
5-硝基-1,10-邻菲罗啉
3) 5,6-diamino-1,10-phenanthroline
5,6-二氨基-1,10-邻菲罗啉
1.
Synthesis of 5,6-diamino-1,10-phenanthroline;
5,6-二氨基-1,10-邻菲罗啉的合成研究
4) 1,10-phenanthroline
1,10-邻菲罗啉
1.
Hydrothermal Synthesis of Decavanadium Oxide Complex with 1,10-phenanthroline;
以1,10-邻菲罗啉为配体的钒氧酸盐配合物的水热合成
2.
Through the complexation of the two N atoms of 1,10-phenanthroline with the .
合成了配合物双(4-氨基苯甲酸)(1,10-邻菲罗啉)锌(Ⅱ),通过元素分析、红外光谱对其进行了表征。
3.
Three new solid complexes of rare earth (Ⅲ) with 2,4,5-Trichlorophenoxyacetic Acid and 1,10-Phenanthroline were synthesized in aqueous solution and the formula is RE(TCP)3·phen (RE=La,Nd,Er;TCP=2,4,5-Trichlorophenoxyacetate;phen=1,10-Phenanthroline).
在水相中合成三种新的稀土·三氯苯氧乙酸·邻菲罗啉固体配合物,其通式为RE(TCP)_3·phen(RE=La,Nd,Er;TCP=2,4,5-三氯苯氧乙酸;phen=1,10-邻菲罗啉)。
5) 5-acrylamido-1,10-phenanthroline
5-丙烯酰胺基-1,10-邻菲罗啉
1.
Using respectively 1-phenyl-3-methyl-4-benzoyl-5-pyrazolone(PMBP,-diketone) and 5-acrylamido-1,10-phenanthroline as the first and second ligand,we synthesized the ternary chelates of yttrium-group rare earth metal ions Dy3+,Er3+,Tm3+ and Yb3+.
镧系金属(Ln)的钇组稀土离子Dy3+、Er3+、Tm3+、Yb3+分别与第一配体1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮(PMBP,β-二酮)、第二配体5-丙烯酰胺基-1,10-邻菲罗啉反应合成了钇组稀土离子-β-二酮-邻菲罗啉衍生物三元螯合物。
2.
Lanthanide metal cations,La3+,Pr3+,Nd3+,Eu3,Dy3+,Er3+,Tm3+ and Yb3+,reacted with the first ligand,1-Phenyl-3-methyl-4-benzoyl-5-pyrazolone(PMBP)and the second ligand,5-acrylamido-1,10-phenanthroline(5-a-1,10-phen),respectively to form eight lanthanide metal cations——diketone-phenanthroline derivative ternary chelates with the uniform formula Ln(PMBP)3(5-a-1,10-phen).
以1-苯基-3-甲基-4-苯甲酰基-5-吡唑啉酮(PMBP)为第一配体、5-丙烯酰胺基-1,10-邻菲罗啉(5-a-1,10-phen)为第二配体,分别与镧系元素(Ln)金属离子La3+、Pr3+、Nd3+、Eu3、Dy3+、Er3+、Tm3+、Yb3+合成了8个镧系金属-β二酮-邻菲罗啉衍生物三元螯合物Ln(PMBP)3(5-a-1,10-phen)。
6) bis(2,2-bipyridine)-5-amino-1,10-phenanthrolineruthenium(II)
二(2,2-联吡啶)(5-氨基-1,10-邻菲咯啉)合钌(II)
补充资料:一水合邻菲罗啉
分子式:C12H8N2.H2O
分子量:198.22
CAS号:5144-89-8
性质:密度1.10。熔点97-101°C。水溶性<0.01 g/100 mL at 21°C。
分子量:198.22
CAS号:5144-89-8
性质:密度1.10。熔点97-101°C。水溶性<0.01 g/100 mL at 21°C。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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