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1)  propargyl alcohol
炔丙醇
1.
From the reactions of camphene with propargyl alcohol,2butyn1ol and 3trimethyl siliconic propargyl alcohol in the presence of 4methylbenzenesulfonic acid,bornyl propargyl ether(2a),bornyl 2butynyl ether (2b) and bornyl 3trimethyl siliconic propargyl ether(2c) are prepared respectively with corresponding yield 74 %,68 % and 63 %.
莰烯在对甲苯磺酸等催化下与炔丙醇、2炔丁醇、3三甲基硅基炔丙醇反应,分别制得冰片基炔丙基醚、冰片基2炔丁基醚和冰片基(3三甲基硅基)炔丙基醚,产率63%~74%。
2)  propinol
炔丙醇
1.
The reaction mechanism, thermodynamic and kinetic behavior of the dipole cycloaddition reaction of benzaldoxime with propinol have been studied by DFT method at B3LYP/6-31G* level.
用密度泛函理论(DFT)方法在B3LYP/6-31G*水平上研究了苯甲醛肟与炔丙醇加成反应的微观机制和热力学、动力学行为。
2.
Z) -3-tri- p -tolystarnyl-1,1-diphenylpropenol was synthesized by the reaction of tri- p -tolytio hydrde with 1,1-diphenylpropinol and characterized by elemental analysis.
利用三(对甲苯基)氢化锡与1,1-二苯基炔丙醇的加成合成了(Z)-3-三(对甲苯基)锡基-1,1-二苯基烯丙醇,通过元素分析、1HNMR、IR光谱、紫外光谱、TGA-DSC热分析等对其进行了结构表征和性质研究。
3)  propargylic alcohols
炔丙醇
1.
Furthermore,we have found that the Yb(OTf)_3-catalyzed reaction of secondary propargylic alcohols with 1,3-dicarbonyl compounds also proceeds smoothly to give the corresponding propargylation products.
进一步,我们发现二级炔丙醇在稀土金属三氟甲磺酸盐催化下也能很好地与1,3-二羰基化合物反应,给出其炔丙基化产物。
4)  propiolic alcohol
丙炔醇
1.
The resulting imidazoline as an inhibitor was compounded with propiolic alcohol and butynediol.
以丙炔醇、丁炔二醇为复配剂对油酸基咪唑啉缓蚀剂进行了复配研究。
2.
The anodic oxidation reactions of butynediol and propiolic alcohol in the bright nickel electroplating were studied using ultraviolet spectrophotometry.
采用紫外分光光度法研究了丁炔二醇和丙炔醇在光亮镀镍过程中的阳极氧化反应,以期进一步认识添加剂在电镀过程中的作用机理。
3.
It is found in the experiments that the synergetic effect of propiolic alcohol,potassium iodide and quaternary ammonium salt has a good corrosion inhibition for zinc in 0.
8 mol/L的盐酸溶液中丙炔醇、碘化钾和季铵盐的协同作用对锌具有很强的缓蚀作用,并对缓蚀剂在不同浓度、不同温度条件下的缓蚀效果进行比较,得出缓蚀剂最佳配比和最佳使用条件。
5)  Propargyl alcohol
丙炔醇
1.
A corrosion inhibitor CH - 10 used in high temperature acid treatment was obtained by compounding this cationic Mannich base with propargyl alcohol.
针对Mannich碱型缓蚀剂存在的溶解性不好和缓蚀率不高等问题,以甲醛、环己酮和苯胺为原料,合成了一种Mannich碱型缓蚀剂CH-9,将其阳离子化后,再与丙炔醇复配,得到了阳离子型高温酸化缓蚀剂CH-10。
2.
A facile method is presented for synthesis of malonaldehyde dianil from propargyl alcohol by oxidizing using chromium trioxide and addition reaction with aniline.
以丙炔醇为原料,经三氧化铬氧化生成丙炔醛后,直接与苯胺反应简便地合成了β-苯胺基丙烯醛缩苯胺。
3.
The inhibition of propargyl alcohol for 1Cr18Ni9Ti stainless steel in hydrochloric acid solution is studied with the cyclic voltammetry and ellipsometry.
采用循环伏安法和椭圆偏振光谱法 ,研究了丙炔醇 (Propargylalcohol,PA)对 1Cr18Ni9Ti不锈钢在含有氯离子的腐蚀环境中的缓蚀作用 ,实验表明Cl-能使 1Cr18Ni9Ti不锈钢发生点蚀 ,而缓蚀剂PA对不锈钢受到Cl-的腐蚀起抑制作用 。
6)  homopropargylic alcohol
高炔丙醇
1.
Promoted by metal dysprosium, aldehydes and ketones could react smoothly with propargyl bromide to afford the corresponding homopropargylic alcohols in good to excellent yields, and no allenic alcohols were found.
在金属镝的促进下,醛、酮可与炔丙基溴反应,高选择性高产率地得到相应的高炔丙醇,没有发现连二烯醇的存在。
补充资料:炔丙醇
  分子式  HOCH2C≡CH
   CAS号  107-19-7
   性质  无色、挥发性带有刺激气味的液体。熔点-52℃。沸点114℃。相对密度0.9485(20/4℃)。折射率nD(20℃)1.43064。粘度(20℃)1.68mPa·s。 闪点(开杯)36℃。蒸气压(20℃)1.55kPa。与水、苯、氯仿、1,2-二氯乙烷、乙醚、乙醇、丙酮、二恶烷、四氢呋喃、吡啶混溶,部分溶于四氯化碳,但不溶于脂肪烃。久置尤其遇光时易泛黄。
   用途  用作生产丙烯酸、丙烯醛的原料、医药中间体,也可用作腐蚀阻止剂、安定剂等
  毒性   有毒。对皮肤和眼睛有严重刺激作用。大鼠经口LD50为0.07g/kg。操作中宜戴防护眼镜及手套。 
   包装储运  由于炔丙醇闪点较低,且在有杂质存在时能发生激烈反应,应特别注意安全。短期贮运,可用洁净无锈的钢制容器。长期存放则宜用不锈钢、玻璃或酚醛树脂衬里容器,并应避免使用铝等材料。按易燃化学品规定贮运。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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