1) Red shifting H-bond
红移氢键
2) red-shifted H-bond
红移型氢键
3) blue-shifted H-bond
蓝移氢键
1.
The blue-shifted H-bonds between HNO(HNS) and (HF)1≤n≤3 are theoretically studied in this paper,using ab initio calculation.
运用量子化学从头算方法研究了HNO(HNS)与(HF)1≤n≤3形成的蓝移氢键。
4) Blue-Shifting Hydrogen Bond
蓝移型氢键
1.
Quantum Chemistry Investigation on Nitrogen Clusters and Blue-Shifting Hydrogen Bond Systems;
氮原子簇合物及蓝移型氢键的量子化学研究
5) improper blue-shifted H-bond
反常蓝移氢键
1.
Since the improper blue-shifted H-bond and dihydrogen bond were found,the unusual phenomena have attracted more and more attentions of scientists.
特别是反常蓝移氢键和双氢键的发现,更加引起了科学家们的广泛关注。
6) PH2…Y blue-shifting H-bond
PH2…Y蓝移氢键
补充资料：红移效应
使用不同的溶剂或引入取代基所引起的化合物的光谱 (通常指紫外-可见光谱)的吸收峰向长波方向的移动。其机理可由跃迁能级发生了变化来阐明。当化合物溶于极性溶剂时产生溶剂化，由于激发态和基态的电荷分布不同而使这两种状态的溶剂化程度不同。例如，溶剂的极性愈大,有机分子的成键π轨道向反键π*轨道的跃迁波长愈长，说明激发态的极性比基态大，能级降低得比基态多，从而发生红移效应。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条