1) Hydrogen bond
氢键
1.
The hydrogen bonding structure and properties of 3,4,5-triydroxybenzyl acid dimer;
3,4,5-三羟基苯甲酸二聚体氢键结构性质
2.
Synthesis of PVA side-chain liquid crystalline polymer material by hydrogen bond assembly;
氢键组装PVA侧链液晶高分子材料的合成
3.
Organic supramolecular layer frameworks based on weak hydrogen bond;
基于弱氢键相互作用形成的层状有机超分子晶体
2) Hydrogen bonding
氢键
1.
The hydrogen bonding structure for the ground state and the lowest excited state of 1,2,3-triazine-water complex;
邻-三氮杂苯—水复合物基态与最低激发态氢键结构
2.
Study on hydrogen bonding in water-ethanol beverage—hydrogen bonding of beer;
醇水饮料中氢键的研究——啤酒的氢键
3.
Theoretical Analysis of Intracellular Ice Growth and Molecular Dynamics Simulation of Hydrogen Bonding Characteristics of Cryoprotective Agent Solutions
胞内冰生长的理论分析及保护剂溶液氢键特性的MD模拟
3) hydrogen bonds
氢键
1.
The application of hydrogen bonding recognition in designing and controlling over supramolecular polymers has attracted great attention recently due to the influence of hydrogen bonds on the thermodynamic properties,microscopic self-assembling,crystallizing and liquid crystallizing behaviors of such polymers.
近年来,由于氢键作用对聚合物的热力学性质、微观自组装、结晶及液晶行为的重要影响,氢键识别在超分子聚合物的分子设计与结构控制方面的应用受到广泛关注。
2.
Focused on the disruption and regeneration of hydrogen bonds between amides groups of adjacent nylon 6 chains to prepare high strength and high modulus fiber by ultra high molecular weight nylon 6.
为了用超高分子质量尼龙6制备高强高模纤维,对超高分子质量尼龙6分子间的酰胺基氢键的屏蔽和再生进行了研究。
3.
The infinite chains are connected by hydrogen bonds involving the coordination water molecular and SO42-.
此配合物含有三种分别沿[100]、[010]、[110]方向排列的无限长链,并通过其配位水分子与位于层间位置的SO42-形成氢键而连接成为超分子结构。
4) hydrogen-bonding
氢键
1.
Dynamic Simulations of the Hydrogen-bondings on the Proximal Side of the Heme in Terms of ABEEM/MM Method;
血红素近轴侧基氢键的ABEEM/MM分子动力学模拟
2.
Synthesis and Characterization of Novel Supramolecular Liquid Crystals Through Intermolecular Hydrogen-bonding;
基于氢键自组装超分子液晶的制备及表征
3.
The hydrogen-bonding interactions between NCS and PLLA were studied with FTIR,TA and WAXD methods.
利用红外光谱、热分析、WAXD及SEM探讨了复合膜的氢键作用和相容性。
5) Hydrogen-bond
氢键
1.
Ab initio calculation on hydrogen-bond of system of gas hydrate and kinetics inhibitor of acylamide;
酰胺类动力学抑制剂在水合物体系中形成氢键从头计算
2.
Ab initio Studies on the Structures of the Hydrogen-bond Clusters C_5H_ (10)NH(NH_3)_n(n=1—3);
六氢吡啶和氨形成的氢键团簇C_5H_(10)NH(NH_3)_n(n=1～3)结构的从头算研究
3.
The expression of hydrogen-bond acidity of compounds having hydroxyl or carboxyl;
含羟基或羧基化合物的氢键酸度的表达式
6) H-bond
氢键
1.
PVP/PAn self-assembly multilayer films had been fabricated through layer-by-layer self-assembly technique via H-bond interaction.
基于分子间的氢键作用利用层层自组装技术制备了PVP/PAn自组装多层膜,通过紫外-可见光谱、红外光谱、原子力显微镜、扫描电镜、X-射线反射光谱等手段对该自组装多层膜的组装过程、成膜驱动力、表面形貌、结构及膜厚作了详细探讨;2。
2.
In virtue of H-bond,π-π and CH-π interactions,the 3-D network of the complex is formed.
在氢键,π-π堆积和CH-π作用下,化合物形成了3D结构。
3.
The optimized structures, energies and natural population analysis (NPA) were presented and analyzed in terms of their possible correlation with the interaction energies and the H-bond separations.
计算结果表明[Emim]+和[Cys]-之间存在较强的氢键相互作用,其稳定化能主要来源于[Cys]-中羰基O的孤对电子lp(O)和[Emim]+中C—H反键轨道σ*(C—H)之间的相互作用,lp(O)→σ*(C—H)。
补充资料：氢键
| 氢键 hydrogen bond 一个与电负性高的原子X共价结合的氢原子（X—H）带有部分正电荷，能再与另一个电负性高的原子（如Y）结合，形成一个聚集体X—H…Y的化学结合作用。X、Y原子的电负性越大、半径越小，则形成的氢键越强。例如，F—H…F是最强的氢键。氢键表面上有饱和性和方向性：一个H原子只能与两个其他原子结合，X—H…Y要尽可能成直线。但氢键H…Y之间的作用主要是离子性的，呈现的方向性和饱和性主要是由 X和Y之间的库仑斥力决定的。氢键可以在分子内形成，称为内氢键；也可以在两个分子之间形成。分子间的氢键可使很多分子结合起来，形成链状、环状 、层状或立体的网络结构。 氢键的键能比较小，通常只有17～25千焦／摩尔。但氢键的形成对物质的性质有显著影响 ，例如使熔点和沸点升高；溶质与溶剂之间形成氢键，使溶解度增大 ；在核磁共振谱中氢键使有关质子的化学位移移向低场；在红外光谱中氢键X—H…Y的形成使X—H的特征振动频率变小并伴有带的加宽和强度的增加 ；氢键的形成决定蛋白质分子的构象，在生物体中起重要的作用。 |
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