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1)  Michael-type addition reaction
麦克加成反应
1.
Afterthen,a kind of injectable hydrogels was prepared via Michael-type addition reaction of dithiothreitol with this macromer.
通过麦克加成反应在磷酸盐缓冲溶液中制备出一种基于三臂聚乙二醇丙烯酸酯的能快速固化的可注射水凝胶。
2.
A kind of novel three-dimensional crosslinked hydrogel was synthesized via Michael-type addition reaction of dithiothreitol (DTT) as a crosslinker towards the self-assembly of α-CDs with three-arm acryloyl end-capped PEG.
首先以三臂丙烯酰化的聚乙二醇(P-3A)为客体分子,与α-CD 超分子进行自组装形成准轮烷,然后再使其与二硫代苏糖醇(DTT)通过麦克加成反应生成具有超分子结构的化学凝胶。
2)  Michael addition reaction
麦克尔加成反应
1.
Via C-2 and C-6 hydroxyl group of β-cyclodextrin(CD) were functionally modified respectively,the AB2 type β-CD functional monomer with Si-H and double bonds was synthesized by hydrosilylation and Michael addition reaction,and the molecular structure of the functional monomer was characterized with 1H NMR,MALDI-TOF MS and element analysis.
分别对-β环糊精(CD)上6位伯羟基和2位仲羟基进行功能化改性,通过硅氢加成和麦克尔加成反应合成了带有硅氢键和双键的AB2型-βCD功能单体;并采用1H NMR、飞行时间质谱和元素分析对该功能单体的结构进行了表征。
3)  reversal of the Michael addition
反麦克尔加成反应
4)  enantioselective michael addition
不对称麦克尔加成反应
5)  Michael addition reaction
迈克尔加成反应
1.
2-cyanoethyl-5-norbornene-2-carboxaldehyde was synthesized through a Michael addition reaction of acrylonitrile and 5-norbornene-2-carboxaldehyde using tert-butyl alcohol and potassium hydroxide as catalyst at room temperature.
此中间体由丙烯腈与5-降冰片稀-2-醛经叔丁醇与氢氧化钾催化发生迈克尔加成反应而生成。
2.
A lower generation dendritic twelve ester has been synthesized from ethylenediamine and acrylic twelve ester by means of Michael addition reaction in the solvent of methanol .
以乙二胺和丙烯酸十二酯为原料 ,甲醇为溶剂 ,采用迈克尔加成反应合成了低代的树枝状十二酯。
3.
In this paper,hyperbranched functional molecular skeleton terminated with ester and amido groups,with carbon chain length of 12 and 16 were synthesized by divergent method by means of C12 and C16 fatty amine as the core,and then separately with methyl acrylate and ethylenediamine alternating Michael addition reaction and amidation condensation reaction.
采用发散合成法,分别以C12和C16脂肪胺为核心,与丙烯酸甲酯和乙二胺交替进行迈克尔加成反应和酰胺化缩合反应,合成了碳链长度为12和16、端基分别为酯基和氨基的超支化功能分子骨架。
6)  Michael reaction
迈克尔加成反应
1.
Six carboxyl acids DEMB was produced with Michael Reaction using triethylamine as alkaline catalyst and solvent, malonic acid and itaconic acid as raw materials.
以三乙胺为催化剂和溶剂,衣康酸和丙二酸为原料,采用迈克尔加成反应合成了含有6个羧基的多元羧酸DEMB。
补充资料:麦考密克
麦考密克(1809~1884)
McCormick,Cyrus Hall
     美国工业家,发明家。近代收割机的发明者之一。1834年他创制的一台收割机获得专利   , 1837 年开始小量制造。1847年在伊利诺伊州芝加哥市建立工厂,开始大规模生产收割机,为麦考密克收获机公司 (1902年与其他公司合并成为国际收获机公司)奠定了最初的基础。
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