D301 resin has been used as a base in the Heck reaction of heteroaryl halides with olefins in the absence of phosphine ligand at a low Pd concentration.

Ligand free Ullmann coupling reactions of aryl halides catalyzed by Pd/C were studied in O/W Triton X10 microemulsion(ME) in comparison with biphase systems.

Recent advances in the palladium-catalyzed Ullmann-type coupling of aryl halides in- cluding reductive coupling and oxidative coupling reactions have been reviewed.

The reductive coupling of aryl halides to form the corresponding biaryls was effected with high selectivity in water,using formic hydrazide as a reducing agent in the presence of a catalytic amount of Pd/C.

It is an important method to form C Ar—N by palladium-catalyzed amination of aryl halides.

With the application of sterically hindered, electron-rich alkylphosphines, this reaction is now applicable to a broad range of aryl halides.

Firstly, a cyanation process of aryl halides with K4[Fe(CN)_6]-3H_2O as the cyanating reagent was studied.

Study of the trifluoromethylation of aromatic halides;

In the presence of copper(Ⅰ) iodide as the catalyst and under the protection of inert gas,aromatic halides including bromobenzene,iodobenzene,iodotuluene and iodonitrobenzene reacted with sodium trifluoroacetate to give the corresponding trifluoromethylated compounds in moderate to good yields.

Research on application of PLS and PM3 algorithms in QSPR to reductive dehalogenation of selected halogenated aromatic hydrocarbons in anoxic sediment;

Trie application of carboxymethyl-β-cyclodextrin on the solubi-lization of halogenated aromatic hydrocarbons is investigated.

PM3 hamiltonian was used to compute descriptors of some halogenated aromatic hydrocarbons, such as pola-rizability, dipole, etc.

One of the typical halogenated aromatic, 1,4-DCB is choosed as the research target pollutants in this study.