1) thermoregulated transfer catalysts
温控相转移催化剂
1.
The prepared thermoregulated phosphine ligands were respectively reaction with palladium chloride by in-situ synthesis, obtained four kinds of thermoregulated transfer catalysts (Pd/FAPEPP, Pd/MGPPE, Pd/TMPGP and Pd/TAPEPP).
为了解决以上问题,本文尝试将温控相转移催化剂用于催化松香和α-蒎烯加氢反应。
2) thermoregulated phase-transfer catalysis
温控相转移催化
1.
Aiming at the problems that the classical aqueous/organic biphase system is unsuitable for the hydroformylation of higher olefins,six kinds of improved methods including the thermoregulated phase-transfer catalysis were introduced in detail.
综述了对液/液两相催化高碳烯烃氢甲酰化制备高碳醇的研究进展,针对经典的水/有机两相体系不能用于催化高碳烯烃氢甲酰化的问题,全面介绍了适用于水/有机两相体系中高碳烯烃氢甲酰化的温控相转移催化法等6种改进方法。
2.
In order to solve this problem, six kinds of improved methods including thermoregulated phase-transfer catalysis are introduced in detail.
结合作者近年来的研究工作 ,对液/ 液两相催化高碳烯烃氢甲酰化的研究进展作一综述 ,针对经典的水/有机两相体系不能用于高碳烯烃氢甲酰化的问题 ,全面介绍了适用于高碳烯烃水/有机两相氢甲酰化的温控相转移催化等 6种改进方法。
3.
A novel concept of Thermoregulated Phase-Transfer Catalysis (TRPTC) recently p.
本课题组最近提出的“温控相转移催化”正是这一领域的最新进展之一。
3) thermoregulated phase transfer catalysis
温控相转移催化
1.
Emphasis is put on the general principles of thermoregulated phase transfer catalysis (TRPTC) and thermoregulated phase separable catalysis (TPSC), based on thermoregulated ligands, and on their applications in hydroformylation of higher olefins, CO selective reduction of nitroarenes, and hydrogenation of olefins.
着重介绍了以温控配体为基础的新型液 /液两相催化过程温控相转移催化 (thermoregulatedphasetransfercatalysis ,TRPTC)和温控相分离催化 (thermoregulatedphase separablecatalysis,TPSC)的基本原理及其在高碳烯烃氢甲酰化、芳香硝基化合物的CO选择性还原及烯烃加氢等反应中的应用 。
2.
Nonionic water soluble complex Ru 3(CO) 9(PETPP) 3 with the function of thermoregulated phase transfer catalysis was prepared.
基于以乙氧基链为亲水基的水溶性膦配体具有非离子表面活性剂的逆反“温度 水溶性”特性 (浊点 ) ,即室温下溶于水的膦配体在高于其浊点的温度下会因赖以产生水溶性的氢键破坏而从水中析出的特性 ,金子林等[1～ 3]提出了“温控相转移催化”的概念并成功地用于水溶性极低的高碳烯烃水 /有机两相氢甲酰化反应 。
3.
With thermoregulated ligands as main line, the general principles of thermoregulated phase transfer catalysis (TRPTC) and thermoregulated phase-separablecatalysis (TPSC) were introduced, based on thermoregulated ligands.
介绍了基于温控膦配体的新型液/液两相催化体系温控相转移催化(TRPTC)和温控相分离催化(TPSC)的基本原理。
4) Solvent regulated phase-transfer catalyst
溶剂控制相转移催化剂
5) reaction-controlled phase-transfer catalyst
反应控制相转移催化剂
1.
The catalytic performance of a reaction-controlled phase-transfer catalyst,quaternary ammonium heteropolyphosphatotungstate,for propylene epoxidation was investigated using aqueous hydrogen peroxide as oxidant and HPO~(2-)_4 or H_2PO~-_4 as additive.
以H2O2为氧化剂,以磷酸氢盐或磷酸二氢盐为添加剂,研究了反应控制相转移催化剂(磷钨杂多酸季铵盐)催化丙烯环氧化的反应性能。
2.
Heteropoly blue Q 7PMo 12O 42 (Q=C 5H 5NC 16H 33) has been designed and synthesized as reaction-controlled phase-transfer catalyst for catalytic epoxidation of cyclohexene and catalytic oxidation of benzalcohol with H 2O 2 as the oxidant.
设计合成了第一个由磷钼杂多蓝作为反应控制相转移催化剂的反应体系 ,用于对环己烯进行催化环氧化 ,苯甲醇进行催化氧化 。
6) phase-transfer catalyst
相转移催化剂 <化>
补充资料：高分子相转移催化剂
分子式：
CAS号：
性质：经过高分子化的相转移催化剂。催化效率高，不污染反应物和产物，催化剂回收容易，环境污染较小。主要包括亲脂性的有机离子化合物(季铵盐和磷鎓盐)和非离子型的冠醚类化合物。
CAS号：
性质：经过高分子化的相转移催化剂。催化效率高，不污染反应物和产物，催化剂回收容易，环境污染较小。主要包括亲脂性的有机离子化合物(季铵盐和磷鎓盐)和非离子型的冠醚类化合物。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条