The aim of this thesis is to synthesize new coordination polymer with one-dimensional chain structure on the basis of aromatic carboxylic acid ligands and transition metal ions, to study the influence of ligands structure and synthetic conditions to the formation of one-dimensional chain, and to explore the relationships between structure and property.

Five ternary complexes have been synthesized from terbium with aromatic carboxylic acid(p-methylbenzoic acid,p-aminobenzoic acid,sulfosalicylic acid,methoxybenzoic acid,m-chlorobenzoic acid)and acrylonitrile and aslo characterized by means of elemental analysis,thermal analysis,FT-IR spectra and UV spectra.

Five ternary complexes have been synthesized from terbium with aromatic carboxylic acid(p-methylbenzoic acid,p-aminobenzoic acid,sulfosalicylic acid,methoxybenzoic acid,salicylic acid) and acrylamide,and also characterized by means of elemental analysis,thermal analysis,FT-IR spectra and UV spectra.

Five ternary complexes have been synthesized from europium with aromatic carboxylic acid(p-methylbenzoic acid, methoxybenzoic acid, m-chlorobenzoic acid, benzoic acid, p-hydroxylbenzoic acid) and acrylamide; and also characterized by means of elemental analysis, thermal analysis, FT-IR spectra and UV spectra.

Determination of aromatic acids in terephthalic acid wastewater by ultra-performance liquid chromatography/ultraviolet detection

Aryl halides can be easily carbonylated into aromatic acids in good to high yields under mild conditions,with dichlorobis(triphenylphosphine) palladium(Ⅱ) as catalyst and normal pressure of CO,by using polyethyleneglycol(PEG) as phase transfer catalyst in NaOH-PhOMe aqueous media.

Determination of acromatic carboxylic acids by β-cyclodextrin modified capillary zone electrophoresis;