1) in situ RAFT polymerization
原位RAFT聚合
1.
Temperature sensitive polymer brushes with densely grafted poly(N-isopropyl acrylamide) side chains on a random copolymer backbone were successfully synthesized by the combination of atom transfer radical polymerization (ATRP),"click chemistry" and in situ RAFT polymerization.
ATRP、“click chemistry”和原位RAFT聚合相结合,成功的制备了具有温度响应性的聚异丙基丙烯酰胺(PNIPAM)聚合物刷。
2) RAFT polymerization
RAFT聚合
1.
The linear macro RAFT agent PS-SC(S)Ph was prepared by RAFT polymerization of S using 2-(ethoxycarbonyl)-2-propyl dithiobenzoate (ECPDB) and AIBN as RAFT agent and initiatior.
在选择性溶剂中,大分子RAFT试剂PSSC(S)Ph和AIBN引发剂存在下,进行4乙烯基吡啶(4VP)和二乙烯基苯(DVB)的RAFT聚合,一步合成了稳定的平头型胶束。
2.
Compared with other living/controlled free radical polymerization methods, major advantages of the RAFT polymerization are i) very similar recipe and processes to the traditional free radical polymerization, ii) a larger variety of monomers, and iii) higher polymerization rate.
相对于其它“活性”自山基聚合,RAFT聚合的主要优点是:ⅰ) 可以直接应用传统自由基聚合的配方和工艺基础;ⅱ) 适用单体范围广;ⅲ) 同时还能保证较高的聚合速率。
3) aqueous RAFT polymerization
水相RAFT聚合
4) Surface RAFT polymerization
表面RAFT聚合
5) Ambient temperature RAFT polymerization
室温RAFT聚合
1.
Ambient temperature RAFT polymerization is a facile and versatile technique, particularly in favor of the synthesis of well-defined polymers from thermo-sensitive or thermo-degradable monomers.
在许多领域尤其热敏感或热降解单体的聚合等,室温RAFT聚合方法将成为方便简捷的技术。
补充资料:原位
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性质:源于拉丁语。指在原来的,正常、自然的部位或位置。
CAS号:
性质:源于拉丁语。指在原来的,正常、自然的部位或位置。
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