1) Double-decker
[英]['dʌbl'dekə] [美]['dʌbəl'dɛkɚ]
双层配合物
2) binuclear complex
双核配合物
1.
The binuclear complex [Cu 2(TS)(H 2O)]·H 2O, where TS donates the binuclearing ligand derived from the schiff base N,N'_bis(3_carboxylsalicylidene)trimethylenediamine, was obtained through the selfdecomposition of mononuclear complex Na 2CuTS·H 2O in the methanol/water.
利用单核配合物Na2 CuTS·H2 O在溶剂中的不稳定性质 ,自分解并重新组装得到了双核配合物 [Cu2 (TS)(H2 O) ]·H2 O 。
2.
A synthetic method of LnH2salen complexes was described and a series of binuclear complexes were obtained.
合成了稀土Ｎ，Ｎ－亚乙基双（水杨醛缩亚胺）（Ｈ２ｓａｌｅｎ）双核配合物，通过元素分析、热分析、紫外、红外、远红外光谱、磁化率及１Ｈ、１３ＣＮＭＲ谱与Ｔ１的测定，确定了他们与前人合成的配合物有所不同，其化学组成为［Ｌｎ２（Ｈ２ｓａｌｅｎ）３（ＮＯ３）４］（ＮＯ３）２·３Ｈ２Ｏ（Ｌｎ＝Ｌａ，Ｐｒ，Ｎｄ，Ｓｍ，Ｇｄ，Ｔｂ，Ｅｒ，Ｙｂ及Ｙ），并对它们的配位作用、波谱及可能应用进行了探讨。
3.
Six new binary complexes Cr(L-A)3[L=H, 2-OCH3, 4-OCH2CH3; A=2-(COO)C6H4CONHC6H4-,COOCH2CH2CONHC6H4-]and four new binuclear complexes Cr(L-A)3?/2CuX2[L=2-OCH3 , 4-OCH2CH3 : X=C1 , Br] were synthesized and characterized by elemental analysis, infrared and ultraviolet spectra as well as molar conductors.
本文报道了六种二元配合物Cr（L-A）_3[L=H，2-OCH_3，4-OCH_2CH_3；A=2-（COO）C_6H_4CONHC_6H_4-，COOCH_2CH_2CONHC_6H_4-]和四种双核配合物Cr（L-A）_3·3/2CuX_2[其中L=2-OCH_3，4-OCH_2CH_3；X=Cl，Br]的合成。
3) dinuclear complex
双核配合物
1.
Studies on the Spectra of Rare Earth Dinuclear Complexes with o-Phenanthroline Hydrate;
稀土邻菲咯啉双核配合物的光谱研究
2.
By using a tricyanometalate precursor TpFeⅢ(CN)3- (Tp=hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged dinuclear complex, (Tp)FeⅢ(CN)3CuⅡ(bpy)2ClO4·CH3OH (1) (bpy=2, 2′-bipyridine), has been prepared and characterized.
采用[TpFeⅢ(CN)3]-作为构筑基块,合成并表征了一个氰基桥联双核配合物[(Tp)FeⅢ(CN)3CuⅡ(bpy)2]ClO·4CH3OH(1)。
3.
The dinuclear complex[Pb(η2-o-FcCOC6H4COO)(μ2-η2-o-FcCOC6H4COO)(phen)]2·CH3OH is prepared with Pb(OAc)2·3H2O,o-ferrocecarbonyl benzoic sodium(o-FcCOC6H4COONa,Fc=(η5-C5H5)Fe(η5-C5H4))and 1,10-phenanthroline(phen) as materials in the mixing solvent of methanol and ethanol.
3H2O与邻羧基苯甲酰二茂铁钠盐[o-FcCOC6H4COONa,Fc=(η5-C5H5)Fe(η5-C5H4)]和1,10-邻菲啰啉(phen)在甲醇和乙醇的混合溶剂中反应,合成了一个双核配合物[Pb(η2-o-FcCOC6H4COO)(μ2-η2-o-FcCOC6H4COO)(phen)]2。
4) dinuclear complexes
双核配合物
1.
Advances in the artificial hydrolysis enzyme models of dinuclear complexes developed in resent years are reviewed.
本文综述了近年来双核配合物作为人工酶的研究进展 ,讨论了这类配合物的催化水解机理及影响因
6) Ruthenium-Diphosphine Complex
双膦配合物
补充资料：双[1-(4-二甲氨基)苯基2-苯基1,2-二硫代乙烯合镍]
分子式：
CAS号：
性质：紫黑色单斜晶体。熔点277～278℃。溶于苯、甲苯、三氯甲烷等大多数有机溶剂。红外频率υ(C＝S)1190、1165、1140cm-1,红外频率υ(S-C-C-S)880cm-1。由对二甲氨基安息香、五硫化二磷在二噁烷(二氧六环)中反应后,加入镍(Ⅱ)盐溶液制得。用作光学非线性材料。
CAS号：
性质：紫黑色单斜晶体。熔点277～278℃。溶于苯、甲苯、三氯甲烷等大多数有机溶剂。红外频率υ(C＝S)1190、1165、1140cm-1,红外频率υ(S-C-C-S)880cm-1。由对二甲氨基安息香、五硫化二磷在二噁烷(二氧六环)中反应后,加入镍(Ⅱ)盐溶液制得。用作光学非线性材料。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条