A Cd(II) adduct [Cd(DBTC)2(4,4'-bipy)] (2) was synthesized by mixing 4,4'-bipyridyl with the precursor [Cd(DBTC)2]2 (1) (DBTC=N,N-dibenzyl dithiocarbamate anion) and characterized by X-ray crystallography structural analysis and IR spectra respectively.

The chelating properties for heavy metals of modified corn starch which contains dithiocarbamate group(DTCS) have been studied.

Four metal complexes, which were shown as [Cd(DBTC) 2] 2 (1), [Hg(DBTC) 2] (2), [Nd(DBTC) 3·2H 2O] and [Nd(DBTC) 3(HMPA) 2] (3) (where DBTC=N,N-dibenzyl dithiocarbamate, HMPA=hexa~methyl~phos~pho~ra~mide), were synthesized and characterized by IR spectra.

,oxidative coupling,and synergistic combination with ashless thiocarbamate,zinc thiocarbamate,sulfur and phosphorusfree molybdate,non-active organic borate and organic alkali metal salt.

A Method to Compound the Intermediate of Thiocarbamate;

Synthesis of Thiocarbamates via Selenium-mediated Carbonylation of Aniline with Thiols;

Determination of Seven Thiocarbamate Herbicides in Black Tea and Green Tea by Liquid Chromatography Coupled with Tandem Mass Spectrometry Detection

On the basis of the results of the corresponding proof experiments and the report in literature,the mechanism of selenium-mediated carbonylation of aniline with thiols to thiocarbamates is proposed.

In this paper,the main methods to synthesize thiocarbamates such as hydrolysis or alcoholysis of thiocyanate,rearrangement reaction,phosgene derivatives method and carbonylation of nitro compounds or amines are summarized.

The purpose of this thesis is to explore a creative method for the synthesis of thiocarbamates.