1) carbonyles
羰合物类
2) multicarbonyl compound
多羰基类化合物
1.
Six novel chiral multicarbonyl compounds(6a～6f) in yields of 50%～70% were synthesized by the asymmetric Michael addition-elimination reaction of chiral 5-(S)-5-(l-menthyloxy)-3,4-dihalo-2(5H)-furanones with some carbonyl nucleophilic reagents containing active methylene.
通过手性源5-(S)-5-(l-孟氧基)-3,4-二卤-2(5H)呋喃酮与含活泼亚甲基的羰基类亲核试剂发生的不对称Michael加成-消除反应,合成了6个新的手性多羰基类化合物(产率50%～70%),其结构经1H NMR,13CNMR,IR和ES-HRMS确证。
3) carbonyles
羰络物类
4) Cyclicβ-diketon compounds
环状β-二羰基类化合物
5) carbonyl compound
羰基化合物
1.
Recent development in the regioselectivity of the addition of prenylmetals to carbonyl compound;
异戊烯金属有机化合物与羰基化合物加成的区域选择性研究进展
2.
Improvement of Determination Method of Carbonyl Compound in Methanol;
甲醇中羰基化合物含量测定方法的改进
3.
Application of recombinant genetic engineering strains in asymmetric reduction of carbonyl compounds
重组基因工程菌在不对称还原羰基化合物中的应用
6) carbonyl compounds
羰基化合物
1.
Competition between carbonyl compounds and phenylethylene in reduction by borohydride anion exchange resin(BER)over PdCl_2 as the catalyst;
钯催化下 BER 对羰基化合物和苯乙烯的竞争还原
2.
The researches of carbonyl compounds in the atmosphere and its exchange between plants and the atmosphere;
植物排放的羰基化合物及其与大气的交换
3.
Crotylation of carbonyl compounds with crotyl bromide mediated by different metal nanoparticles in water;
水相中不同纳米金属促进的羰基化合物和巴豆基溴的丁烯基化反应(英文)
补充资料：环戊二烯金属羰合物
分子式：
CAS号：
性质：通式(C5H5)xMy(CO)z。此类化合物分子中含有环戊二烯基和羰基两种配体。过渡金属环戊二烯基羰基配位化合物,数量多,用途广,多数有颜色。常见的羰合物举例如下: (1)( η5-C5H5)2M(CO)2；M=Ti,Zr,Hf (2) ( η5-C5H5)M(CO)4；M=V,Nb,Ta (3) ( η5-C5H5)2M2(CO)6；M=Cr,Mo,W (4)( η5-C5H5)2M(CO)3；M=Mn,Tc,Re (5) ( η5-C5H5)2M2(CO)2(μ2-CO)2；M= Fe,Ru (6) ( η5-C5H5)M(CO)2；M= Co,Rh,Ir (7) ( η5-C5H5)2Ni(μ2-CO)2；以及( η5-C5H5)2Pt2(CO)2制备方法归纳为下述几种。 (1)金属羰合物与环戊二烯反应：2Fe(CO)5+2C5H6[ ( η5-C5H5)Fe(CO)2]2+6CO+H2 (2)二茂金属与CO或金属羰合物反应：( η5-C5H5)2Mn+CO( η5-C5H5)Mn(CO)3( η5-C5H5)2Ni+Ni(CO)2]4[( η5-C5H5)Ni(CO)]2+2CO(3)金属羰合物或金属羰合卤化物与茂试剂反应：W(CO)6+NaC5H5→Na[(η5-C5H5)W(CO)3][( η5-C5H5)W(CO)3]2[μ-ClRh(CO)2]2+2TiC5H52( η5-C5H5)Rh(CO)2+2TiCl (4)环戊二烯金属卤化物跟一氧化碳和还原剂反应:( η5-C5H5)2-MoCl2+CO( η5-C5H5)2Mo(CO)
CAS号：
性质：通式(C5H5)xMy(CO)z。此类化合物分子中含有环戊二烯基和羰基两种配体。过渡金属环戊二烯基羰基配位化合物,数量多,用途广,多数有颜色。常见的羰合物举例如下: (1)( η5-C5H5)2M(CO)2；M=Ti,Zr,Hf (2) ( η5-C5H5)M(CO)4；M=V,Nb,Ta (3) ( η5-C5H5)2M2(CO)6；M=Cr,Mo,W (4)( η5-C5H5)2M(CO)3；M=Mn,Tc,Re (5) ( η5-C5H5)2M2(CO)2(μ2-CO)2；M= Fe,Ru (6) ( η5-C5H5)M(CO)2；M= Co,Rh,Ir (7) ( η5-C5H5)2Ni(μ2-CO)2；以及( η5-C5H5)2Pt2(CO)2制备方法归纳为下述几种。 (1)金属羰合物与环戊二烯反应：2Fe(CO)5+2C5H6[ ( η5-C5H5)Fe(CO)2]2+6CO+H2 (2)二茂金属与CO或金属羰合物反应：( η5-C5H5)2Mn+CO( η5-C5H5)Mn(CO)3( η5-C5H5)2Ni+Ni(CO)2]4[( η5-C5H5)Ni(CO)]2+2CO(3)金属羰合物或金属羰合卤化物与茂试剂反应：W(CO)6+NaC5H5→Na[(η5-C5H5)W(CO)3][( η5-C5H5)W(CO)3]2[μ-ClRh(CO)2]2+2TiC5H52( η5-C5H5)Rh(CO)2+2TiCl (4)环戊二烯金属卤化物跟一氧化碳和还原剂反应:( η5-C5H5)2-MoCl2+CO( η5-C5H5)2Mo(CO)
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条