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1)  solveny
溶剂作用力
2)  solvent effect
溶剂作用
1.
This paper reviewed the results about the solvent effect on coal liquefaction in recent years.
综述了近年关于煤液化反应中溶剂作用方面的研究成果,以及研究溶剂作用的新分析手段和研究方法。
3)  solvation [英][sɔl'veɪʃən, sɔ:l-]  [美][sɑl'veʃən, sɔl-]
溶剂化作用
1.
Studies on the Solvation of Fullerene (C_(60)) in Toluene Medium;
C_(60)-甲苯溶液溶剂化作用
2.
Solution characteristics of NH_3-H_2O-LiBr ternary solution influenced by different LiBr concentration were calculated theoretically by solvation model and the experiments were carried on.
采用溶剂化作用模型,理论计算分析了LiBr对NH3-H2O-LiBr三元溶液组成的影响,并进行了实验。
4)  solvent effect
溶剂化作用
1.
In order to elucidate the solvent effect of species and their relevant microcosmic properties in the solution, DFT quantum mechanical calculations were firstly performed on various species of aluminate ions and ion pairs at the UHF/BLYP/DNP level.
应用量子化学从头算密度泛函理论以及DFT/COSMO溶剂模型,基于UHF/BLYP/DNP水平对高苛性比中等浓度铝酸钠溶液中各类离子(分子)的溶剂化作用进行研究。
2.
The solvent effects of C24H30O8 have also been investigated based on Onsager self-consist.
采用密度泛函理论(DFT)方法,在B3LYP/6-31G*水平下全优化得到了该化合物的分子几何构型和电子结构;依据Onsager自恰反应场(SCRF)模型考察了其在氯仿、丙酮、二甲亚砜及水等溶剂中的溶剂化作用;基于气相优化结构进行了B3LYP/6-31G*振动分析,用0。
5)  solvent swelling effcct
溶剂溶胀作用
6)  Solvophobic interaction
疏溶剂相互作用
1.
Usually, the electrostatic interaction becomes stronger, while solvophobic interaction weaker.
由于非水溶剂相对于水的物理性质的变化,通常其中的静电相互作用变强,而疏溶剂相互作用变弱。
补充资料:溶剂电缩作用
分子式:
CAS号:

性质:反应物和过滤态均被溶剂化层所包围,当过滤态存在极性,增加了电荷密度,从而增加了溶质与溶剂化层分子的静电作用力,引起溶剂化层的收缩,减少了活化体积。此即称溶剂电缩,一般约为-10~-20cm3/mol。

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