Pinacol rearrangement in CO_2 enriched high temperature liquid water;

Kinetics of pinacol rearrangement in high temperature liquid water;

Study on rearrangement of semipinacone and cycloheptane cation with ab initio method;

2-Arylglutarates with high yields(73%～87%) were prepared by addition-rearrangement reactions of phenylsulfonylacetates containing 4-nitro or 2-nitro with α,β-unsaturated esters under K2CO3-TEBA phase transfer catalyst conditions.

The transition-states of rearrangement reaction of the stable structure of F 2CCLiBr have been determined, and the potential barriers of rearrangement reactions have been obtained at B3LYP/6-31G(d,p) level.