The rescue and organization of group poisoning with dimethyl sulfate;

Determination of dimethyl sulfate in quaternary ammonium salt surfactant by headspace gas chromatography

Two novel room-temperature ionic liquids, 1-methyl-3-methylimidazole methyl sulfate and 1-butyl-3-methylimidazole methyl sulfate were formed by the reaction of dimethyl sulfate with methylimidazole and butylimidazole at room temperature respectively.

8%,while m-aminophenol was used as material,ethyl bromide as ethyl reactant, dimethylsulfate as methyl reactant,and synthesis process was optimized by means of changing solvent and feeding appropriate phase-transfer catalyst etc.

Under the reaction conditions as follows: n(2,7-dihydroxynaphthalene0∶n(doimethylSulfate)=1∶3, reaction temperature of 80℃, reaction time of 3h and by means of dropwise of dimethylsulfate, the yield of 2,7-dimethoxynapthalene was up to 783%.

9%,while m-aminophenol is used as reactant,tetrahydropyran as hydroxyl shielding effect agent,acetic anhydride as acyl protection reactant and amidogen mono-substituted alternative reactant,ethyl bromide as ethyl reactant,dimethylsulfate as methyl reactant.

3,3′-dithiobispropionate as the start material was reacted with indole,5-bromo-1H-indole and 5,6-dichloro-1H-indole anion respectively to get ester 2a～2c.