1) Boc-L-glutamic acid 5-benzyl ester
叔丁氧羰基-L-谷氨酸-&gamma
2) Boc-Glu-OBzl
叔丁氧羰基-L-谷氨酸α苄脂
3) Boc-Glu(OBzl)-OH
叔丁氧羰基-L-谷氨酸-γ-苄脂
4) N tert Butoxycarbonyl L Tyrosine
N-叔丁氧羰基-L-酪氨酸
5) N-tertbutyloxycarbonyl-L-histidine
N-叔丁氧羰基-L-组氨酸
1.
Cyclo(L-His-L-Pro) was synthesized from protected N-tertbutyloxycarbonyl-L-histidine and L-proline methyl ester hydrochloride via DCC condensation,deprotection of tertbutyloxycarbonyl group with another solution of hydrogen chloride,cyclization with NaHCO3 solution.
许多环二肽具强的生理活性,以N-叔丁氧羰基-L-组氨酸和L-脯氨酸甲酯盐酸盐为原料,经DCC缩合得直链二肽,再经HCl/Et2O脱Boc保护,弱碱性条件下成环,得环(L-组-L-脯)二肽。
6) N-(tert-Butoxycarbonyl)-L-serine
N-叔丁氧羰基-L-丝氨酸
1.
A facile method was developed to synthesize N-(tert-Butoxycarbonyl)-O-benzyl-L-serine with a yield rate of 53% by using sodium tert-pentoxide as a base for the reaction between N-(tert-Butoxycarbonyl)-L-serine and benzyl bromide under mild conditions.
对文献报道和工业制备N-叔丁氧羰基-O-苄基-L-丝氨酸的方法进行了改进,以叔戊醇钠代替NaH和Na/NH3作为碱处理N-叔丁氧羰基-L-丝氨酸后,再与苄溴在温和条件下反应制得了N-叔丁氧羰基-O-苄基-L-丝氨酸,产率为53%。
补充资料:叔丁氧羰基-L-谷氨酸-&gamma
CAS: 13574-13-5
分子式: C17H23NO6
分子量: 337.37
熔点: 65-68℃
中文名称: BOC-L-谷氨酸5苄脂; 叔丁氧羰基-L-谷氨酸-γ-苄脂; BOC-L-谷氨酸5-苄酯
英文名称: n-[(1,1-dimethylethoxy)carbonyl]-l-glutamic aci 5-(phenylmethyl) ester; boc-l-glutamic acid 5-benzylester; Boc-Glu(OBzl)-OH; Boc-L-glutamic acid 5-benzyl ester
分子式: C17H23NO6
分子量: 337.37
熔点: 65-68℃
中文名称: BOC-L-谷氨酸5苄脂; 叔丁氧羰基-L-谷氨酸-γ-苄脂; BOC-L-谷氨酸5-苄酯
英文名称: n-[(1,1-dimethylethoxy)carbonyl]-l-glutamic aci 5-(phenylmethyl) ester; boc-l-glutamic acid 5-benzylester; Boc-Glu(OBzl)-OH; Boc-L-glutamic acid 5-benzyl ester
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
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