1) 4-chloro-3-oxo-butanoic acid ethyl ester
4-氯代乙酰乙酸乙酯
2) ethyl 4-chloro-3-oxobutanoate
4-氯乙酰乙酸乙酯
1.
Asymmertric reduction of ethyl 4-chloro-3-oxobutanoate to ethyl (S)-4-chloro-3-hydroxybutanoate with Aureobasidium pullulans SW0202 cells as catalyst was performed in an aqueous/organic solvent biphasic system.
研究了水/有机溶剂两相体系中,出芽短梗霉SW0202细胞催化4-氯乙酰乙酸乙酯(COBE)不对称还原制备(S)-4-氯-3-羟基丁酸乙酯(CHBE)的过程。
2.
AIM: To optimize the asymmetric reduction of ethyl 4-chloro-3-oxobutanoate (COBE) to (S)-ethyl 4-chloro-3-hydroxybutanoate [(S)-CHBE] directly catalyzed by yeast (Saccharomyces cerevisiae) fermentation broth.
目的优化酵母发酵液直接催化4-氯乙酰乙酸乙酯(COBE)合成(S)-4-氯-3-羟基-丁酸乙酯((S)-CHBE)的反应条件。
3.
By cultivation and immobilization,several yeast strains were selected to catalyzethe asymmetric(reduction) of ethyl 4-chloro-3-oxobutanoate(COBE) to optically active ethyl 4-chloro-3-hydroxybutanoate ((CHBE)) in organic solvent.
将酵母细胞用海藻酸钙包埋后用于有机相催化不对称还原4-氯乙酰乙酸乙酯制备光学活性的4-氯-3-羟基丁酸乙酯,从中筛选得到具有较高立体选择性和还原能力的菌株假丝酵母SW0401,将此菌株的细胞固定化细胞作为研究对象,系统考察了固定化条件、固定化细胞大小、反应溶剂、初始底物浓度、辅助底物、固定化细胞热处理和抑制剂对还原反应的影响。
3) ethyl 4-chloroacetoacetate
4-氯乙酰乙酸乙酯
1.
Mole ratio of ethyl 4-chloroacetoacetate and isopropyl nitrite was 1∶1.
4-氯乙酰乙酸乙酯经亚硝酸异丙酯肟化、硫脲环合一步反应制得去甲氨噻肟酸乙酯。
2.
The asymmetric reduction of ethyl 4-chloroacetoacetate(COBE) to ethyl(R)-(+)-4-chloro-3-hydroxybutyrate((R)-CHBE) by the recombinant cells in an aqueous phase was investigated.
将重组细胞用于催化4-氯乙酰乙酸乙酯不对称还原,合成出具有光学活性的(R)-(+)-4-氯-3-羟基丁酸乙酯。
3.
Aureobasidium pullulans SW0202 with high enantioselectivity for asymmetric reduction of ethyl 4-chloroacetoacetate(COBE) to ethyl (S)-4-chloro-3-hydroxybutyrate (S-CHBE) was isolated.
通过筛选得到不对称还原4-氯乙酰乙酸乙酯(COBE)合成(S)-4-氯-3-羟基丁酸乙酯(S-CHBE)对映选择性好的微生物菌株出芽短梗霉菌(Aureobasidiumpullulans)SW0202。
4) ethyl 4-chloro-3-oxobutanoate (COBE)
4-氯乙酰乙酸乙酯(COBE)
5) ethyl-4-chloroacetoacetate
4-氯乙酰基乙酸乙酯
6) Ethyl γ-chloroacetoacetate
γ-氯代乙酰乙酸乙酯
补充资料:4-氯代乙酰乙酸乙酯
CAS:638-07-3
分子式:C6H9ClO3
分子质量:164.59
沸点:103℃
熔点:-8-106℃
中文名称:4-氯代乙酰乙酸乙酯
γ-氯代乙酰乙酸乙酯
4-氯乙酰乙酸乙酯
英文名称:4-chloro-acetoacetic acid ethyl ester
4-chloro-3-oxo-butanoic acid ethyl ester
ethyl 4-chloro-3-oxobutanoate
ethyl 4-chloroacetoacetate
用途:医药中间体。
分子式:C6H9ClO3
分子质量:164.59
沸点:103℃
熔点:-8-106℃
中文名称:4-氯代乙酰乙酸乙酯
γ-氯代乙酰乙酸乙酯
4-氯乙酰乙酸乙酯
英文名称:4-chloro-acetoacetic acid ethyl ester
4-chloro-3-oxo-butanoic acid ethyl ester
ethyl 4-chloro-3-oxobutanoate
ethyl 4-chloroacetoacetate
用途:医药中间体。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条