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1)  low-temperature distillation of BF3
三氟化硼低温精馏
2)  cryogenic rectification
低温精馏
1.
On the base of recent achievements of isotope separation,chemical engineering and cryogenic engineering,preparation of material gas,strengthening of heat transfer,design of new packing,structure of cryogenic rectification tower,cascade type,energy organizing for the innovation of production of stable isotope carbon-13 were studied.
概述了国际上稳定同位素碳-13的分离技术现状;分析了不同装置的技术特点;结合CO低温精馏技术关键及近年低温技术、化工技术的最新成果,从原料气制备工艺、换热器设计、新型填料设计、精馏塔结构、级联形式、能量组织利用等方面分析了低温精馏技术分离碳-13的技术创新途径。
3)  Cryogenic distillation
低温精馏
1.
Hydrogen isotope separation and simulation technology with cryogenic distillation system;
氢同位素的低温精馏分离及模拟技术
2.
A rigorous thermodynamic model was used to study the characteristics of cryogenic distillation column of hydrogen isotope system having feedback stream.
应用严格的热力学模型研究了带有侧线返回进料的氢同位素低温精馏塔的分离特性 。
3.
In order to uncover the inherent relationship of operating parameters in cryogenic distillation separation of hydrogen isotopes,the influences of Wr(heat power of reboiler) on deuterium extraction efficiency,column pressure drop and liquid level were studied under total reflux mode.
为探求全回流模式下低温精馏氢同位素分离过程中有关操作参数的内在联系,研究了再沸器加热功率对脱氘率、床层压降、液氢液位等的影响。
4)  boron fluoride
三氟化硼
1.
These(preliminary) studies indicate that the boron fluoride with nitromethane or acetone system with higher separation factor is superior to the anisole system used currently,but a more detailed study is.
采用苯甲醚、硝基甲烷、丙酮、甲基异丁基甲酮4种络合剂分别与三氟化硼合成出了4种络合物体系。
2.
The isotopes of boron,~(10)B and ~(11)B,were separated by means of a gas-liquid chemical exchange reaction and distillation involving the isotopic equilibrium between gaseous boron fluoride and a liquid boron fluoride-donor molecular addition complex.
设计了合成络合物体系的实验反应器,并用这些络合剂分别与三氟化硼合成了4种络合物体系。
5)  boron trifluoride
三氟化硼
1.
The com plexes between these new donors and boron trifluoride (BF .
在介绍化学交换精馏法分离同位素硼10原理的基础上, 分析了目前工业化过程分离同位素硼10 存在的问题, 指出新的络合剂硝基甲烷(CH3NO2 )、丙酮(Acetone)、甲基异丁基酮(MIBK)、二异丁基酮(DIBK)等用于从三氟化硼分离硼10 具有更高的分离系数, 形成的络合物具有更好的稳定性, 其中CH3NO2 是现有同位素硼10分离工艺过程较为理想的替代络合剂。
2.
Although the ionic conductivities of methanol and pure boron trifluoride diethyl etherate (BFEE) are very low, methanol containing small amount of boron trifluoride diethyl etherate is good proton electrolyte with maximum ionic conductivity of 20 mS/cm.
甲醇和三氟化硼乙醚(BFEE)本身离子电导率很低,向甲醇溶液中加入少量BFEE可以形成良好的质子电解质溶液。
3.
Several separation routes of isotope boron 10 are described,but unique chemical exchange fractional distillation of boron trifluoride-anisole is adopted for the enrichment of boron 10 in large scale nowadays in the world.
叙述了同位素硼10的分离技术,唯有三氟化硼—苯甲醚化学交换精馏法是当今世界美、俄等国工业生产规模所采用的技术路线。
6)  BF_3
三氟化硼
1.
Commercial Scale Process of BF_3 in Cylinder;
瓶装三氟化硼的大规模生产
2.
Medical BF_3 And Its Safety Code in Use;
医用级三氟化硼及其在使用中的安全注意事项
3.
To prepare the epoxy coating by heat-control soldfied in BF_3 microcapsule;
制备三氟化硼微型胶囊热控固化环氧涂料
补充资料:三氟化硼低温精馏
分子式:
CAS号:

性质:分离硼同位素最简单的方法,适用于大规模生产。BF3精馏在沸点-101.7℃附近进行,低温液体作冷却剂,高效绝热塔精馏,分离系数为1.007。11BF3比10BF3易于挥发,10B富集在塔底。一个生产装置在全回流情况下,富集的10B浓度达96%,年产量为百公斤级。

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