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1)  transannular reaction
跨环反应
2)  cyclization [英][,saikli'zeiʃən]  [美][,saɪklɪ'zeʃən, ,sɪklɪ-]
环化反应
1.
Theoretical Studies on the Intramolecular Cyclization of (Z)-8-(Trimethylstannyl)oct-6-enal;
顺-8-三甲基锡烷基-6-辛烯醛分子内环化反应立体选择性的理论研究
2.
Cyclization in situ of Isoprene Polymerization Catalyzed by Nd-Al Bimetallic Complex;
钕-铝双金属配合物催化异戊二烯聚合的原位环化反应
3.
Synthesis of 3 Acylhydrazino 5 (2,4 dichlorophenyl) 1,3,4 oxadiazole and Studies on Their Cyclization;
2-酰肼基-5-(2,4-二氯苯基)-1,3,4-噁二唑的合成及环化反应研究
3)  cyclization [英][,saikli'zeiʃən]  [美][,saɪklɪ'zeʃən, ,sɪklɪ-]
环合反应
1.
In this paper,the title compound was synthesized through cyclization reaction of p-methylbenzoic acid,p-chloromethylbenzoic acid and p-nitrilbenzyl chloride with 4,6-diaminoresorcinol dihydrochloride.
分别以对甲基苯甲酸和对氯甲基苯甲酸以及对氰基氯苄为主要原料,与4,6-二氨基间苯二酚盐酸盐进行环合反应,合成了2,6-二(4-氯甲基苯基)苯并[1,2-d;5,4-d′]二噁唑,并采用IR,1H NMR和元素分析等分析方法对产物结构进行了确认。
2.
The intermediate of Tinoxicam,4-hydroxy-3-methyl-2H-thieno-1,2-thiazine-2-(methyl) carboxylate-1,1-dioxide(MHTTCD) was synthesized from methyl 3-amino-2-thiophene methyl carboxylate through four steps: chlorosulfonylation,methylamination,N-alkylation,and cyclization.
环合反应在甲醇钠的甲醇溶液中进行,合适的甲醇钠浓度为1mol/L。
3.
The synthesis of furan phenol through cyclization were studied, catalyzed by aluminium alkoxide and the affect of the catalyst weight against the selection of furan phenol and the feeding in or distilling out of the alcohol against the reaction yield of product.
采用醇铝作为呋喃酚环合反应催化剂,研究催化剂用量与呋喃酚选择性的关系,以及在反应体系中添加或采出醇对反应收率的影响。
4)  cyclic reaction
循环反应
1.
The cyclic reaction characters of CaCO3 and three dolomites with CO2 was experimentally investigated.
对分析纯碳酸钙和三种白云石与CO2的循环反应特性进行实验研究。
2.
The cyclic reaction characteristic of CaO/Ca12Al14O33, limestone and dolomite with CO2 were investigated by using TGA.
合成了3种不同质量配比的钙基CO2吸收剂CaO/Ca12Al14O33,并对CaO/Ca12Al14O33、石灰石、白云石的循环煅烧/碳酸化特性进行试验研究,以考察吸收剂的转化率随循环反应次数的变化规律。
5)  cyclization reaction
成环反应
1.
Then 4-oxy-7-methyl-1,8-naphththyridine-3-carboxylic acetate was synthesized by cyclization reaction in different heat carr.
在250℃的反应温度下,分别以二苯醚、石蜡油和邻苯二甲酸二乙酯为热载体进行成环反应,得到4-氧-7-甲基-1,8-萘啶-3-羧酸乙酯的收率分别为88。
6)  Ring-opening reaction
开环反应
1.
Potassium maleate-containing ionomers were prepared by ring-opening reaction of epoxidized styrene-butadiene-styrene block copolymer(SBS).
用环氧化(苯乙烯-丁二烯-苯乙烯)嵌段共聚物(SBS)开环反应合成了含顺丁烯二酸钾基的SBS离聚体,考察了离子基团不同含量对含顺丁烯二酸钾基的SBS离聚体力学性能的影响,研究了离聚体/聚丙烯(PP)共混物的力学性能和耐溶剂性能,以及离聚体对氯醇橡胶(CHR)/SBS共混物的增容效果。
2.
Epoxidized styrene-butadiene-styrene triblock copolymer(ESBS) can react with potassium hydrogen maleate by ring-opening reaction in the presence of phase transfer catalyst and ring-opening catalyst.
利用环氧化苯乙烯-丁二烯-苯乙烯嵌段共聚物(ESBS)的环氧基与顺丁烯二酸氢钾(HKM)在相转移催化剂和开环催化剂存在的条件下开环反应制得钾离聚体。
3.
Sodium sulfonated SBS ionomer was made from epoxidized styrene-butadienestyrene triblock copolymer(ESBS) and NaHSO_3 by ring-opening reaction in the presence of phase transfer catalyst,ring-opening catalyst and pH value regulator.
结果表明,ESBS开环反应制备磺酸钠离聚体的最佳条件为:ESBS在甲苯中的质量浓度为12 g/100 mL;n(NaHSO3)/n(Epoxy)=1。
补充资料:跨环反应
分子式:
CAS号:

性质:中等大小的环(成环碳原子n=8~11),环的一边可与另一边接近,在反应中氢可以跨环迁移到环的另一边。这种类型的反应叫做跨环反应。例如:醇与十碳环的环氧化合物反应,主要得到的是跨环产物,烷氧基和羟基处于1,6-位。

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