1) (R)-(-)-2-Hydroxymethylpyrrolidine
D-脯氨醇
2) D-proline
D-脯氨酸
1.
Study on the Synthesis of D-Proline by Asymmetric Transformation;
不对称转换法制备D-脯氨酸的工艺研究
2.
Racemization of L-Proline and Asymmetric Transformation of D-Proline;
L-脯氨酸的消旋及不对称转化法合成D-脯氨酸
3.
Using L-proline as raw material, (2R,3R)-tartaric acid as resolution agent, D-proline was prepared by asymmetric transformation, i.
以L脯氨酸为原料、(2R,3R)酒石酸为拆分剂,采用不对称转换的方法将L-脯氨酸转换成D-脯氨酸。
3) prolinol
脯氨醇
1.
Using inexpensive,convenient obtained NaBH_4-I_2-THF system,N-Cbz or Boc protected prolines were reduced into corresponding prolinols in mild condition with high chemical selectivity and good to high yields,and the protecting groups were not influenced.
采用价廉易得的NaBH_4-I_2-THF体系还原N-Cbz或Boc保护的脯氨酸,可以得到相应的脯氨醇,反应条件温和,产率高,化学选择性好,保护基不受影响。
4) L-prolinol
L-脯氨醇
1.
Under the above mentioned conditions, the yield of L-prolinol could be reached 90 and the optical purity of L-prolinol was up to 97,α_D=+30.
用Zn(BH4)2还原L-脯氨酸制备了L-脯氨醇。
2.
A new chiral auxiliary,non-cross-linked polystyrene(NCPS) supported L-prolinol was synthesized using L-prolinol as initiating material by four steps contained amino protected,etherification,polymerization,deprodection of amino group,and the overall yield was 50.
以L-脯氨醇为原料,经过氨基保护、成醚、聚合、脱叔丁氧羰基(Boc)4步反应合成了一种新的手性助剂——线型聚苯乙烯支载脯氨醇,总产率为50。
5) Hydroxyprolinol
羟脯氨醇
6) D-prolinamide
D-脯氨酰胺
1.
New synthetic route for D-prolinamide;
D-脯氨酰胺的合成新工艺
2.
As an important pyrrolidine derivative, D-Prolinamide shows its excellent asymmetric source potential both in synthesizing chiral Pharmaceuticals and asymmetric reactions, such as CDDP, TRF, Remoxipride and Neuroleptic.
D-脯氨酰胺(D-Prolinamide)作为一种重要的光学活性吡咯衍生物,无论是用作拆分剂和手性试剂,或作为手性中间体合成某些手性药物,其在各种不对称合成反应中都显示出了优良的不对称源性能。
补充资料：D-脯氨醇
分子式：C5H11NO
分子量：101.15
CAS号：68832-13-3
性质：暂无
制备方法：暂无
用途：暂无
分子量：101.15
CAS号：68832-13-3
性质：暂无
制备方法：暂无
用途：暂无
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条