2) novel alkaline catalyst
新型碱性催化剂
1.
Based on experiments, the formulation and preparation process for synthesis of propylene glycol monomethyl ether with novel alkaline catalyst are determined.
研制开发了新型碱性催化剂制备丙二醇单甲醚。
3) chiral catalysts
手性催化剂
1.
The electronic and steric effects of substituted groups,the structures of chiral catalysts and chiral reagents and the reaction system on optical activity of products are summarized.
本文从化学催化法、手性试剂法和酶催化法3个方面综述了近年来芳香酮的不对称还原进展,概述了芳香酮取代基的电子效应与空间效应、手性催化剂和手性试剂的结构、反应体系等对产物光学活性的影响,以及全细胞酶和分离酶等不同生物催化体系中芳香酮结构对产物光学活性的影响,并展望了不对称还原的研究及应用前景。
2.
The development of the preparation of chiral catalysts, the catalytic mechanism and the process in the asymmetric catalytic hydrogenation(ACH) are summarized.
总结了不对称催化加氢技术中手性催化剂的制备、催化机理以及催化工艺的研究熏未来不对称催化对加氢技术的发展趋势提出了一些看法。
3.
Optically active alaninol had been widely used in stereoselective organic synthesis, such as chiral catalysts, the synthesis of the organometallic compounds, modifier of the catalysts and reactants, and so on.
同时 ,手性的 α-氨基丙醇已广泛地应用在不对称合成中 ,包括作为手性催化剂、合成有机金属、作为催化剂和反应试剂的手性修饰物、合成醇衍生物作为手性固定相拆分消旋化合物等
4) chiral catalyst
手性催化剂
1.
Preparation of heterogeneous chiral catalysts and their application to asymmetric hydrogenation;
多相手性催化剂的制备及其对不对称加氢反应的催化作用
2.
Two kinds of chiral catalysts,imidazoline-phenol and pyrrolidine-imidazoline,were designed and synthesized with 2-hydroxyphenylacetic acid,praline and 1,2-diphenylethylenediamine as the start materials.
以1,2-二苯基乙二胺和邻羟基苯乙酸以及脯氨酸为原料,设计并合成了咪唑啉-酚,四氢吡咯-咪唑啉两类手性催化剂,初步研究了它们在催化不对称Michael加成反应中的催化活性。
3.
The asymmetric oxidative coupling of 2-naphthol and its derivative was carried out by using(S)-diphenyl-(α-pyrrolidyl)methanol-CuCl complex as a chiral catalyst.
(S)-二苯基-(α-吡咯烷基)甲醇与氯化亚铜的配合物作为手性催化剂用于2-萘酚及其衍生物的不对称催化氧化偶联反应,产率44。
5) new catalyst
新型催化剂
1.
This paper describes the major features of contemporary organic catalytic technology and introduces some overseas new catalysts recently applied and researched for organic synthesis,pollution control,polymers and petroleum refining and petrochemical process.
介绍现代有机催化发展的主要特点,阐述近10年来世界上在有机合成、污染控制、高分子化工、石油化工中的新型催化剂以及在研催化剂,简介我国催化剂研究的现状并对未来研究趋势作了预
2.
The progress in synthetic methods of coumarin compounds has summarized,including the new methods implicating microwave irradiation and new catalysts,ion liquids and so on.
包括微波辐射法的应用,新型催化剂的应用,离子液体等新方法。
6) novel catalyst
新型催化剂
1.
Methods for producing broad/bimodal molecular mass distribution polyethylene(PE) were introduced with the emphasis of elaboration on the multizone circulating reactor technology,the novel catalyst technology and the oscillating operation process.
介绍了制备相对分子质量分布曲线呈宽峰或双峰分布聚乙烯的主要方法,着重阐述多区循环反应器技术、新型催化剂技术和振荡操作等单反应器技术;综述了各种技术的优缺点及研究现状并对其工业化应用前景进行了展望。
补充资料:手性催化剂
分子式:
CAS号:
性质:立体选择合成中应用的某种具有光学活性的催化剂。在手性催化剂诱导下,使生成的对映体之一过量。例如,3-甲基戊二酮在手性催化剂(S)-2,2′-双(二苯基磷)-1,1′-联萘[(S)-BINAP]二氯化钌配位化合物的催化氧化反应,对映体过量达99%。
CAS号:
性质:立体选择合成中应用的某种具有光学活性的催化剂。在手性催化剂诱导下,使生成的对映体之一过量。例如,3-甲基戊二酮在手性催化剂(S)-2,2′-双(二苯基磷)-1,1′-联萘[(S)-BINAP]二氯化钌配位化合物的催化氧化反应,对映体过量达99%。
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