2) cyclododecanone
环十二酮
1.
2-Oxocyclododecylsulfonamide(C) had been synthesized by amination of 2-oxocyclododecylsulfonic acid chloride, obtained from the cyclododecanone(A) via 2-oxocyclododecylsulfonic acid(B).
以环十二酮(A)为起始原料,经磺化反应制备得到2-氧代环十二烷基磺酸盐B,B经过氯化和胺解反应制备得到2-氧代环十二烷基磺酰胺C,C经过苯氧酰化与胺解反应后合成了10个新的2-氧代环十二烷基磺酰脲类化合物D,它们的结构通过了1HNMR和IR的确证。
2.
N substituted cyclododecanone thiosemicarbazones(4) were synthesized by condensation reaction of cyclododecanone and N substituted thiosemicarbazide.
通过环十二酮与 N -取代氨基硫脲的缩合反应 ,合成了一系列 N -取代环十二酮缩氨基硫脲 ,经Mn O2 氧化关环 ,得到 1 5种未见文献报道的标题化合物 ,其结构经 IR,1 3C NMR,元素分析的确证 。
3.
The preparation of cyclododecanone and its application in organic synthesis of perfumes,pesticides and materials were reviewed in details.
综述了环十二酮的制备方法及其在香料、农药、材料合成中的应用,同时对各种制备方法进行了简要的评价。
3) cyclododecane
环十二烷
1.
Ethanol buffered chloroaluminate ionic liquids consisted of AlCl 3 with 1 alkyl pyridinium or 1 alkyl 3 methyl imidazolium quaternary ammonium salts (QAS), such as 1 butylpyridinium chloride, 1 butyl 3 methylimidazolium chloride, 1 propyl 3 methylimidazolium chloride and 1 ethylpyridinium bromide, are novel reaction medium for selective cyclization of 1 dodecene to cyclododecane.
在氯化 1 丙基 3 甲基咪唑 (PMImCl)、氯化 1 丁基 3 甲基咪唑 (BMImCl)、氯化 1 丁基吡啶 (BPCl)和溴化 1 乙基吡啶(EPBr)季铵盐与AlCl3 构成的室温离子液体介质中 ,首次发现正十二碳烯 (简称十二烯 )可以高选择性地发生环化反应生成环十二烷 。
2.
This experiment based upon the process scaleup, and chiefly studied the influences of the reaction temperature and the agitation speed on the oxidation of cyclododecane in presence of dehydrated boric acid catalyst.
本实验从工程放大角度出发,着重研究了以偏硼酸为催化剂,反应温度和搅拌速率对环十二烷氧化反应的影响,在搅拌鼓泡釜中,适宜反应温度为160~170℃,搅拌转速1500rpm以上,通空气量100ml/g烷。
3.
Cyclododecane, a volatile cyclic alkane (C 12H 24),can be brushed or sprayed onto the object while in the liquid state above 60℃ and cools to be solidified immediately.
为了探索脆弱考古出土物的提取和修复方法,利用环十二烷法对一副秦陵石铠甲进行了提取和修复。
4) Cyclododecanol
环十二醇
1.
Research on Production of Cyclodecanon from Cyclododecanol byContinuous Catalytic Dehydrogenation in Liquid-Solid-Phase;
环十二醇液—固相连续法脱氢制环十二酮小试研究
5) twelve-ring,twelve-membered ring
十二元环
6) cyclododecandione
环十二二酮
补充资料:硝酸、环十二烷醇、环十二烷酮的反应产物高沸点馏分
CAS: 72162-23-3
分子式: C12H24O·C12H22O·HNO3
熔点: 85-95℃
中文名称: 硝酸、环十二烷醇、环十二烷酮的反应产物高沸点馏分
英文名称: Nitric acid, reaction products with cyclododecanol and cyclododecanone, by-products from, high-boiling fraction
Cyclododecanol, cyclododecanone, nitric acid reaction product, high-boiling fraction
分子式: C12H24O·C12H22O·HNO3
熔点: 85-95℃
中文名称: 硝酸、环十二烷醇、环十二烷酮的反应产物高沸点馏分
英文名称: Nitric acid, reaction products with cyclododecanol and cyclododecanone, by-products from, high-boiling fraction
Cyclododecanol, cyclododecanone, nitric acid reaction product, high-boiling fraction
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参考词条