1) methallyloxyphenol
邻甲代烯丙氧基苯酚
1.
In the preparation of benzofuranol from methallyloxyphenol through Claisen- rearrangement and cyclization, aluminium isopropoxide was used as catalyst,xylene was used as solvent.
以邻甲代烯丙氧基苯酚为原料,异丙醇铝为催化剂,在溶剂二甲苯的条件下,经过Claisen重排和环合反应合成呋喃酚。
2) o-methylaniline
邻甲苯胺
1.
3-Methyl-4-acetaminobenzenesulfonyl chloride(Ⅰ) was prepared from o-methylaniline by protecting the amino group and then reacting with chlorosulfonic acid.
合成步骤如下:(1)邻甲苯胺、对甲氧基苯胺的氨基保护后,分别与氯磺酸反应得3-甲基-4-乙酰氨基苯磺酰氯(Ⅰ)和2-甲氧基-5-乙酰氨基苯磺酰氯(Ⅴ);(2)对氨基乙酰苯胺(Ⅱ)分别与Ⅰ、Ⅴ在w(CH3COOH)=5%的醋酸中反应,所得缩合物水解得产品Ⅳ、Ⅶ。
2.
o-Fluorobenzoic acid was synthesized by Schiemann-reaction of o-methylaniline to give o-fluorotoluene which was oxidized by HNO 3 in an autoclave to abtain the product of 70.
以邻甲苯胺为原料 ,经西曼反应合成邻氟甲苯 ,进而经硝酸氧化法得到邻氟苯甲酸 (收率 93。
3) o-methyl
邻甲基
1.
Two series of sulfonated poly(ether ether ketone)s based on tert-butylhydroquione and o-methylhydroquione were synthesized via aromatic nucleophilic substitution reaction.
以特丁基对苯二酚和邻甲基对苯二酚分别制备两个系列磺化聚醚醚酮。
4) Phenolphthalein
邻甲酚酞
5) o-cresol
邻甲苯酚
1.
Study on extraction of o-cresol with tri-n-butyl phosphate;
磷酸三丁酯络合萃取邻甲苯酚的研究
2.
A Study on the Treatment of O-cresol Wastewater with Catalytic and Oxidation;
催化氧化含邻甲苯酚废水的研究
6) o-tolunitrile
邻甲苯腈
1.
o-tolunitrile was synthesized with catalysis by continuous flow gas-solid process.
采用连续流动塔式气固催化法合成邻甲苯腈,通过正交实验得出最佳反应条件为:反应温度270℃,反应物摩尔比n_(邻甲苯甲酸):n_(氨气)=1:1。
参考词条
补充资料：邻甲苯酚
分子式C7H8O，分子量108.13。亦称甲苯酚。通常甲酚是三种异构体的混和物。无色或呈黄棕色液体。溶于大量水中，溶于乙醇、乙醚、苯、石油醚和甘油。由煤焦油中提取。间甲苯酚结构简式。是甲酚三种异构体中含量最大的。无色液体。熔点11～12℃，沸点202℃，密度（20/4℃）1.034g/cm3。可溶于40倍水中，能与乙醇、乙醚、氯仿混溶。主要用作消毒剂、熏蒸剂和照象显影。还用于制树脂和香料。邻甲苯酚是甲酚的第二种异构体。低熔点结晶，熔点30℃，沸点191～192℃，密度（20/4℃）1.047g/cm3。可溶于40倍水中，能与乙醇、乙醚和氯仿混溶。主要用作溶剂、消毒剂和生产树脂的原料。对甲苯酚是甲酚的第三种异构体。结构简式。晶体。熔点35.5℃、沸点201.8℃。密度（20/4℃）1.0341g/cm3。可随水蒸气挥发。用于生产树脂和用作增塑剂等。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。