1) 1'″-diethylbiferrocenes
1'″-二乙基联二茂铁
2) chiral 1 ferrocenylethanol
1-二茂铁基乙醇
3) 1-alkyl-1'-acetylferrocene
1-烷基-1'-乙酰基二茂铁
1.
A novel synthetic method for 1-alkyl-1'-acetylferrocenes (CnH2n+1-Fc-COCH3, n=2~8, Fc=C5H4FeC5H4) was developed.
用新方法合成了1-烷基-1'-乙酰基二茂铁,该法与传统方法相比易于得到单一产物。
4) ethylferrocene
乙基二茂铁
1.
This thesis is mainly divided into three parts: The first part stated the catalyst bentonite-supported polytrifluromethanesulfosil-oxane (B-PTFMSS) used as cataltst for Friedel-Crafts acylation of ethylferrocene.
本论文主要分为三个部分: 一、膨润土负载的聚三氟甲烷磺酸硅氧烷(B-PTFMSS)催化乙基二茂铁Friedel-Crafts酰化反应,研究了该催化剂的催化选择性,实验证实BPTFMSS对乙基二茂铁的催化选择性很高,得到1’-乙基酰基二茂铁选择性可达93%。
5) diacetylferrocene
二乙酰基二茂铁
1.
Five new 1, 1'-bis (1, 3-dioxo-long-chain alkyl ) ferrocenes with the general formula C5H4FeC5H4 (COCH2COCnH2n+1 )2 (n= 5-9) were synthesized by Claisen condensation of 1, 1'-diacetylferrocene with ester.
用1,1'-二乙酰基二茂铁与酯的Claisen缩合反应合成了5个新的1,1'-二(1,3-二氧代长链烷基)二茂铁,其通式为C5H4FeC5H4(COCH2COCnH2n+1)2,n=5~9。
2.
Using the grinding method three novel ferrocenyldichalcones were obtained with the solid aldol condensation of aromatic aldehyde and diacetylferrocene in the presence of NaOH and K2CO3 mixed catalyst under solvent-free condition.
报道了在室温固相条件下,以氢氧化钠和碳酸钾混合碱为催化剂,用研磨法使芳醛与二乙酰基二茂铁反应合成3种新型二茂铁基双查尔酮。
6) diethylferroene
二乙基二茂铁
1.
The synthetic technology of diethylferroene was obtained:Ethyl bromide and anhydrous aluminium chloride was 1 ∶2.
以三氯化铝为催化剂,溴乙烷为烷基化剂,利用二茂铁的Friedel-crafts反应合成出了二乙基二茂铁,探讨了反应温度、物料摩尔比、反应时间、催化剂用量及投料方式对反应的影响,确定了适宜合成工艺:二茂铁、溴乙烷和无水三氯化铝的摩尔比为1∶2。
补充资料:[1,1'-双(二苯基膦基)二茂铁]二氯化钯
分子式:C34H28Cl2FeP2Pd
分子量:731.71
CAS号:72287-26-4
性质:熔点275-280°C。
分子量:731.71
CAS号:72287-26-4
性质:熔点275-280°C。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条