1) (1R,2R)-diaminocyclohexane
(1R,2R)-环己二胺
3) 2R-diaminocyclohexane
2R-环己二胺
1.
The Schiff base ligand L [N,N′-bis(acetylacetone)-1R,2R-diaminocyclohexane] was synthesized from con- densation reaction of 1R,2R-diaminocychohexane with acetyacetone.
本文以乙酰丙酮和(1R,2R)-环己二胺进行缩合得到N,N′-双(乙酰丙酮)-(1R,2R)-环己二胺的Schiff碱配体L,再分别同CoCl2·6H2O和MnCl2·4H2O进行配位反应,得到了2个配合物[CoLCl2]n(1)和[MnLCl2(C2H5OH)·H2O]n(2),并用元素分析,FTIR和X-射线单晶结构分析进行了表征。
4) (1R,2R)-N,N'-bis(methyl 5-(1,1-dimethylethyl)-3-formyl-4-hydroxybenzoate)-1,2-diaminocyclohexane
(1R,2R)-N,N'-双(5-叔丁基-3-甲酰基-4-羟基苯甲酸甲酯)缩环己二胺
5) (1R,2R)-(+)-1,2-Diamino-1,2-diphenylethane
(1R,2R)-1,2-二苯基乙二胺
6) diaminocyclohexane
环己二胺
1.
Five chiral Schiff-ligands were prepared from (R,R)-1,2-diaminocyclohexane and salicyaldehyde or t-butyl-, bromo-, nitro-substituted salicyaldehydes.
以(R,R)1,2环己二胺为手性源,同水杨醛及带有叔丁基,溴或硝基的取代水杨醛反应合成了5个手性席夫碱配体。
2.
The ligands were synthesized by the reaction of 5 replaced 3-tert-butyl salicylaldehyde derivatives (substituents were N-pyrrolidino, N-piperidino, N-morpholino, N, N\'-dibutylamino and PPh3+Cl) with (R, R)-1,2-diaminocyclohexane.
利用(R,R)-1,2-环己二胺和5位取代的3-叔丁基水杨醛衍生物(取代基分别为N-四氢吡咯基、N-六氢吡啶基、N-吗啉基、N,N\'-二丁胺基和氯化三苯基膦基)反应合成的手性Salen配体,将其与钴离子络合,制备出了5种新型手性Salen(CoCl)金属配合物。
补充资料：1-甲基-2,4-环己二胺
CAS: 13897-55-7
分子式: C7H16N2
中文名称: 1-甲基-2,4-环己二胺
英文名称: 4-Cyclohexanediamine, 1-methyl-2；1,3-Cyclohexanediamine, 4-methyl- (8CI,9CI)；2,4-Diaminomethylcyclohexane；2,4-Diamino-1-methylcyclohexane；4-Methyl-1,3-cyclohexanediamine；1-methyl-4-cyclohexanediamine；4-methyl-3-cyclohexanediamine
分子式: C7H16N2
中文名称: 1-甲基-2,4-环己二胺
英文名称: 4-Cyclohexanediamine, 1-methyl-2；1,3-Cyclohexanediamine, 4-methyl- (8CI,9CI)；2,4-Diaminomethylcyclohexane；2,4-Diamino-1-methylcyclohexane；4-Methyl-1,3-cyclohexanediamine；1-methyl-4-cyclohexanediamine；4-methyl-3-cyclohexanediamine
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