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1)  homocoupling reaction
自偶联反应
1.
In the presence of Pd(OAc)2(2 mol%),DABCO(4 mol%),CuI(2 mol%),NaOAc(3 mmol),MeCN(5 mL)and air,a variety of terminal alkynes(1 mmol)undergo homocoupling reaction smoothly to afford the corresponding diynes in moderate to excellent yields.
2]octane)为配体高效钯催化末端炔烃自偶联反应方法。
2)  Coupling reaction
偶联反应
1.
Recent advances in palladium catalysts for aryl chlorides coupling reaction;
氯代芳烃偶联反应中钯催化剂的研究进展
2.
Study on the coupling reaction of organotins and acid chlorides catalyzed by Pd/C;
Pd/C催化有机锡试剂和酰氯偶联反应的研究
3.
Catalytic activity of natural high molecule anchored palladium in coupling reaction of alkyltin hydride;
天然高分子锚定钯对烷基锡氢化物偶联反应的催化活性
3)  cross-coupling reaction
偶联反应
1.
Sulfoether-functionalized, phosphine-functionalized and un-functionalized imidazolium salts(3a~3d, 4, 5) derived from ferrocene were synthesized and evaluated in the Suzuki-Miyaura cross-coupling reaction.
合成了硫醚官能化、膦官能化及未官能化的二茂铁咪唑盐,并研究了以其作为N-杂环卡宾配体前体对Pd催化的Suzuki-Miyaura偶联反应的影响,发现在4-甲基溴苯与苯硼酸偶联反应中以膦官能化的配体对催化性能提高有利,而硫醚官能化不利于催化性能提高。
2.
Suzuki cross-coupling reaction is one of the most efficient methods for the construction of Caryl-Caryl bonds.
Suzuki偶联反应是合成联芳基结构最有效的方法之一,近年许多用于芳基硼酸与各种卤代芳烃偶合的催化剂相继被开发。
3.
Secondly, the palladium-catalyzed cross-coupling reaction of pentafluoro-5-iodo-1,4-diene 4 w.
在第二部分中,研究了多氟-5-碘-1,4-二烯类化合物4在钯催化下与硼酸和末端炔烃的偶联反应: 1。
4)  Coupled reaction
偶联反应
1.
SG is prepared by coupled reaction.
利用偶联反应合成溴甲酚绿键合硅胶,指出溴甲酚绿键合型改性硅胶作为新一代化学键合相,具有很大的发展潜
2.
In this paper, the authors deal with the composite effect and the conditions of coupled reaction of a heterogeneous system involving hydrophobic rubber as continuous phase and the close coupling modified clay as dispersed phase.
本文着重研究以疏水性的橡胶为连续相、以经偶联改性的粘土矿物为分散相的多相体系的复合效应及其偶联反应条件,并利用红外吸收光谱对亲水性粘土矿物的表面偶联方式进行初步的探讨。
5)  coupling [英]['kʌplɪŋ]  [美]['kʌplɪŋ]
偶联反应
1.
Cyclopalladated Ferrocenylimines Complexes: Synthesis, Characterization and Application in C-C and C-N Coupling Reactions;
二茂铁亚胺环钯化合物的合成、表征及其催化的C-C和C-N偶联反应
2.
An important extension of these reactions such as C-H/olefin, C-H/acetylene, C-H/CO and C-H/CO/olefin couplings, hydroacylation and silylation can be regarded as practical tools, for these reactions exhibit high selectivity, high efficiency and wide applicability.
概述了Ru催化的碳氢键的活化反应 ,包括C—H/烯烃 ,C—H/炔烃和C—H/CO/烯烃偶联反应 ,加氢酰化反应 ,硅化反
6)  Heck reaction
Heck偶联反应
1.
Two heteroannular cyclopalladated ferrocenylimine catalystis 1 and 2 are synthesized and applied to Heck reaction.
含杂环二茂铁亚胺异环环钯化合物结构新颖、独特,其催化的Heck偶联反应具有底物范围广、反应条件温和、催化活性高且催化诱导期短等优点。
补充资料:加特曼重氮盐偶联反应
分子式:
CAS号:

性质:重氮盐ArN2Cl在酸性溶液中用铜粉处理,放出氮气,发生偶联反应。当芳环上有吸电子基团时,偶联生成联苯型化合物Ar-Ar;当芳环上有给电子基团时,偶联生成偶氮化合物ArN=NAr。是合成这两类化合物常用的方法。   2ArN2Cl+2Cu→Ar-Ar(或ArN=NAr)+N2↑+CuCl2

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