1) double nitrogen reaction
重氮反应
2) diazotization
重氮
3) diazo
重氮
1.
Monitoring Layer-by-layer Assembling of Films Containing Diazo-resines by Attenuated Total Reflection Fourier Transform Infrared Spectroscopy;
全反射红外逐层检测含重氮高分子薄膜的生长
2.
The synthetic method of Acid Brown G with mono-sodium salt of H acid,resorcin,p-nitroaniline and 2-amino-4-nitro-phenol as the raw materials was introduced in the paper and at the same time,the conditions of diazo and couple reactions were also investigated.
本文介绍了以H-酸单钠盐、间苯二酚、对硝基苯胺、2-氨基-4-硝基苯酚为主要原料合成酸性棕G染料的方法,并对重氮反应和偶合反应条件进行了研究。
3.
The process of Acid Red 2GL is mainly introduced in this paper,and the conditions of both diazo-couple reaction and complexation reactions are also discussed.
本文主要论述了中性红2GL染料的合成工艺路线,并对重氮偶合反应和络合反应条件进行了讨论。
4) diazotization
重氮化
1.
Aromatic Amines in Organic Synthesis of Diazotization;
芳胺重氮化在有机合成中的应用
2.
The preparation D-phenylalanine from N-carbamoyl-D-phenylalanine by diazotization;
N-氨甲酰-D-苯丙氨酸重氮化法制备D-苯丙氨酸的研究
3.
Theoretical study of reaction mechanism of diazotization of 4-amino-5-nitro-1,3-difluorinbenzene;
4-氨基-5-硝基-1,3-二氟苯重氮化反应机理研究
5) diazoresin
重氮树脂
1.
Monitoring of the Photo Reaction of Self-Assembly Film Based on Diazoresin by FTIR;
红外光谱法研究重氮树脂自组装膜的光化学反应
2.
Self-assembly of Diazoresin and P[ N-(4-hydroxyphenyl)acrylamide via H-bonding Interaction;
聚N-对羟苯基丙烯酰胺与重氮树脂的氢键自组装
3.
Self-assembly and Photovoltaic Property of Covalent-attached Multiplayer Films Based on Poly[(4-carboxyphenyl)acetylene] and Diazoresin;
重氮树脂-聚(4-羧酸苯基)乙炔自组装膜与光电转换
6) diazotisation
重氮化
1.
First, 5-nitro-1 and 4-naphthoquinone are prepared through nitration and oxidization of naphthalene, and then through reduction of nitro into amide, diazotisation of the amide and hydro-lytic action of diazo salt, the juglone is made.
萘经过硝化、氧化生成5-硝基-1,4萘醌,然后硝基还原成氨基、氨基重氮化、重氮盐再水解,最终用新方法制得胡桃醌。
2.
Methoxystilbene and 2-methoxy-4'-nitrostilbene were synthesized from benzyl chloride and nitrobenzyl chloride by the Wittig reaction, and used as intermediates for the synthesis of the final product fluorescent whitener FP(4,4'-bis(2-methoxystyryl)biphenyl) via reduction and diazotisation of the latter followed by reaction with the former in the presence of NaOH.
后者经还原反应、重氮化反应后,在氢氧化钠存在下与前者反应生成最终产品荧光增白剂FP(4,4'-双-2-(甲氧基苯乙烯基)联苯)。
3.
The title compound was prepared from \%o\%aminophenol and \%m\%phenylenediamine by diazotisation, coupling reaction and closure, yield was 80 %.
以邻氨基酚和间苯二胺为原料,经重氮化、偶合、环化制备2 (2 羟基苯基) 5 氨基 2H 苯并三唑化合物,产率为80%。
参考词条
补充资料:格里斯重氮化反应
分子式:
CAS号:
性质:芳香族伯胺在过量的强无机酸存在下与亚硝酸(钠)反应,生成芳香族重氮盐。是芳香族胺重氮化的重要反应。应用广泛,芳环上可含有卤素、硝基、磺酸基、烷基、醛基等。若苯核上同时含有多个吸电子基团,反应比较困难。重氮化合物往往不太稳定,受热迅速分解,操作温度常需控制在5℃以下。重氮盐是极有用的试剂,用于多种芳香化合物的合成。脂肪族伯胺也能发生反应,但产物极不稳定。
CAS号:
性质:芳香族伯胺在过量的强无机酸存在下与亚硝酸(钠)反应,生成芳香族重氮盐。是芳香族胺重氮化的重要反应。应用广泛,芳环上可含有卤素、硝基、磺酸基、烷基、醛基等。若苯核上同时含有多个吸电子基团,反应比较困难。重氮化合物往往不太稳定,受热迅速分解,操作温度常需控制在5℃以下。重氮盐是极有用的试剂,用于多种芳香化合物的合成。脂肪族伯胺也能发生反应,但产物极不稳定。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。