In this thesis, we chose B-type Anderson polyoxoanions as building blocks, employed LnIII, lanthanide and transition-metal coordination complexes, which are decorated or bridged to Anderson polyoxoanions, eight new Anderson polyoxometalates were synthesized.

To go on with works by our group, in this thesis we chose B-type Anderson polyoxoanions as building blocks, employed transition-metal coordination complexes, which are decorated or bridged to Anderson polyoxoanions, six novel B-type Anderson polyoxometalates were synthesized.

Fabrication, Structure and Conductivity of Hybrid Organic/Inorganic Langmuir-Blodgett Films of Polyquinoline/Octadecylamine/Rare Earth-substituted Heteropolyanion;

Preparation and electrochemical behaviour of α-SiMo 3W 9O 40 4- heteropolyanion-polypyrrole film modified electrode;

Hydrotalcite-like compounds, heteropolyanions with different compositions, and their pillared products were synthesized by coprecipitation.

A DFT Study of the Vibrational Frequencies of α-[XMo_(12)O_(40)]~(n-)Heteropolyanions;

Studies on the Interaction Between the Layers and Pillars of Hydrotalcite-Like Compounds Pillared with Heteropolyanions;

The phase transfer chemistry of heteropolyanions was introduced from the facile loss of the coordinated water molecules,the activation of inorganic small molecule and the replacement reactions of ligand.