1) Pinic acid diglycidyl ester
蒎酸
2) pinonic acid
蒎酮酸
1.
2-(3-Acetyl-2,2-dimethylcyclobutyl)acetic acid(pinonic acid) is synthesized using α-pinene as raw material and potassium permanganate as oxidant.
以α-蒎烯为原料、高锰酸钾为氧化剂合成了2-(3-乙酰基-2,2-二甲基环丁基)乙酸(即蒎酮酸)。
2.
Synthesis of pionic acid from α-pinene by permanganate oxidation or ozonolysis, and synthesis of cyclobutane ring derivatives of pinonic acid have been reviewed.
综述了α-蒎烯通过KMnO4氧化和臭氧化合成蒎酮酸,以及由蒎酮酸合成四元环类衍生物的研究现状。
3.
In order to improve the strict conditions and the long reaction time required in the traditional method for preparing pinonic acid,a new method,in which surfactant was used to catalyze the oxidation of α pinene,was brought forward.
为了解决蒎酮酸传统合成方法的条件苛刻和反应时间太长等问题 ,提出用表面活性剂催化氧化α 蒎烯的新方法。
3) nopinic acid
诺蒎酸
1.
The yield of nopinic acid reached over 70.
利用水和叔丁醇的混合溶液作为反应的溶剂,用高锰酸钾氧化β-蒎烯制备诺蒎酸,考察了叔丁醇含量、高锰酸钾和碱用量以及温度对产物收率的影响。
2.
The optimum conditions for preparing nopinic acid are: n(β-pinene) ∶n(KMnO_4) ∶n(NaOH) 1 ∶2.
研究以松节油中的β-蒎烯为原料,通过KMnO4氧化合成诺蒎酸,并对氧化反应步骤中各因素对反应的影响进行了探讨。
3.
METHODS β-Pinene was oxidated with KMnO4 in the presence of pyridine to yield nopinic acid,then acid-catalyzed ring opened to yield dihydrocumic acid,which was hydrogenated with Pd/C and epimerizated to yield trans-4-isopropylhexanecarboxylic acid.
方法β-蒎烯经氧化得到诺蒎酸,诺蒎酸开四元环得到二氢枯茗酸,再经过催化加氢、异构得到反-4-异丙基环己烷甲酸,反-4-异丙基环己烷甲酸转变成酰氯后和D-苯丙氨酸反应得到N-(反-4-异丙基环己烷羰基)-D-苯丙氨酸,即2型糖尿病新药那格列奈的原料药。
4) ets-pinonic acid
cis-蒎酮酸
5) pinonic acid ester
蒎酮酸酯
6) 2-chlo-robornane
盐酸蒎烯
补充资料：α-蒎烯与β-蒎烯和苯酚的聚合物
CAS: 68240-07-3
分子式: (C10H16·C10H16·C6H6O)x
中文名称: α-蒎烯与β-蒎烯和苯酚的聚合物
英文名称: Phenol, polymer with 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane and 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene
.alpha.-Pinene, .beta.-pinene, phenol polymer
分子式: (C10H16·C10H16·C6H6O)x
中文名称: α-蒎烯与β-蒎烯和苯酚的聚合物
英文名称: Phenol, polymer with 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane and 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene
.alpha.-Pinene, .beta.-pinene, phenol polymer
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条