2) reductive coupling
还原偶联
1.
Squalene was successfully synthesized from farnesyl bromide with the highly efficient reductive coupling reagent tri-triphenylphosphine cobalt chloride that was freshly prepared in the laboratory.
通过自制高效偶联试剂三三苯基膦氯化亚钴和自制金合欢基溴的还原偶联反应,成功地合成了角鲨烯。
2.
Under ultrasound irradiation, reductive coupling of aromatic aldehydes mediated by Al/KF or NaF in aqueous media afforded 1,2-diol in 15%~82% yields.
超声辐射下,铝粉在氟化钾或氟化钠的水溶液中,可使芳香醛快速还原或偶联,生成相应的双分子还原偶联产物和少量单分子还原产物,其中还原偶联产物邻二醇的收率达15%~82%。
3.
The mechanism and advantages of smoke suppression via reductive coupling were discussed and the requirements for reductive coupling smoke suppressants were summarized.
聚氯乙烯常用的抑烟剂钼 ( )化合物系在凝聚相中以 Lewis酸机理抑烟 ,文中叙述低价过渡金属化合物 (包括低价铜的亚磷酸酯络合物及低价过渡金属的草酸盐和甲酸盐等 )对 PVC的还原偶联抑烟 ,讨论了还原偶联抑烟机理及其优越性 ,对还原偶联抑烟剂的要求 ,并介绍几类可供用于聚氯乙烯的此类抑烟剂及其效果和应用前
3) in situ coupling reaction
原位偶联反应
4) Carbonyl reductive coupling reaction
羰基还原偶合反应
5) Reduction
[英][rɪ'dʌkʃn] [美][rɪ'dʌkʃən]
还原反应
1.
Study on Reduction Behaviours between Lead-rich Slag and Sinter;
富铅渣与铅烧结块在还原反应中的差异研究
2.
Palladium catalyzed reduction of isopropylidene alkylidene malonates with formate ion under phase transfer conditions;
相转移条件下亚烃基丙二酸亚异丙酯的钯催化还原反应
6) reductive reaction
还原反应
1.
Assay to the reductive reaction of 2-aminoethyl sulfate using high performance liquid chromatography.;
高效液相色谱法对2-氨基乙基硫酸酯还原反应的测定
2.
This article has dealt with the replacement of Fe chips with Fe powder in the reductive reaction of titanyl sulfate solution.
介绍了铁粉代替铁屑在酸解钛液还原反应中的应用。
3.
Two synthetic routes starting from 1,3-dihydroxyacetone and formamidine acetate as well as imidazole-4,5-dicarboxylic acid as starting material were investigated, and the reductive reaction of ethyl imidazole-4-carboxylate was also investigated.
本文对以1,3-二羟基丙酮和醋酸甲脒为原料和以4,5-二羧酸咪唑为原料合成4(5)-羟甲基咪唑的两条工艺进行了研究并优化,同时对4(5)-羧酸咪唑乙酯的还原反应进行了探索性实验。
补充资料:还原偶联
分子式:
CAS号:
性质:有机化合物分子在还原剂作用下发生的偶联反应。例如:硝基苯在碱性甲醇溶液中和锌粉作用,即发生还原偶联反应生成偶氮苯: 2C6H5NO2+4Zn+8NaOHC6H5N:+NC6H5通过还原偶联反应,可以合成许多结构对称的有机化合物。
CAS号:
性质:有机化合物分子在还原剂作用下发生的偶联反应。例如:硝基苯在碱性甲醇溶液中和锌粉作用,即发生还原偶联反应生成偶氮苯: 2C6H5NO2+4Zn+8NaOHC6H5N:+NC6H5通过还原偶联反应,可以合成许多结构对称的有机化合物。
说明:补充资料仅用于学习参考,请勿用于其它任何用途。
参考词条