1) monosulfoxide
单亚砜
1.
Benzodithiepane 3 one (1) was asymmetrically oxidized successfully to give monosulfoxide (6) in 60% yield with 100% ee by using modified Sharpless oxidation of cumene hydroperoxide oxide reagent.
采用改良的Ｓｈａｒｐｌｅｓｓ氧化条件，以氢过氧化枯烯为氧化剂，成功地对二硫醚１进行了不对称氧化得到单亚砜６，其光学纯度为１００％，产率为６０％。
2) sulfoxide
[英][sʌl'fɔksaid] [美][sʌl'fɑk,saɪd]
亚砜
1.
Substituted reaction of palladium (Ⅱ) in the presence of dialkyl-sulfoxides;
二烷基取代亚砜萃取钯(Ⅱ)的配位取代反应
2.
Study on the Mechanism of Palladium Extraction by Sulfoxide KSO;
亚砜KSO萃取Pd（Ⅱ）的机理
3.
Study on Composition and structure of Sulfoxide Pd(Ⅱ)Complex;
亚砜KS0与Pd（Ⅱ）萃合物的组成及结构研究
3) sulphoxide
[sʌl'fɔksaid]
亚砜
1.
Solvent Extraction of Au(I)from Gold-Thiourea Leaching Solution by Alkyl Benzothiazole Sulphoxides;
烃基-苯并噻唑亚砜从硫脲介质中萃取金的性能研究
2.
Extraction of penicillin G with sulphoxide extractants;
亚砜类萃取剂萃取青霉素G的工艺研究
3.
Six sulphoxide compounds were enantioseparated with a cellulose-based chiral stationary phase,Chiralcel OD-H,in the normalphase mode.
在纤维素型手性固定相Ch iralcel OD-H正相条件下对6个亚砜化合物进行了拆分,考察了流动相中极性醇添加剂的含量、柱温等对保留及手性拆分效果的影响。
4) sulfoxides
亚砜
1.
The synthesis of sulfoxides and the physical properties of DEHSO;
亚砜的合成及DEHSO的物理性质
2.
The progress on the synthesis of sulfones by oxidation of sulfides or sulfoxides is reviewed with 50 references.
对氧化硫醚或亚砜成为砜的方法作一评述,参考文献50篇。
3.
Sulfoxides as a class of important compounds are generally used as intermediates for the construction of various chemically and biologically significant molecules,as well as for the synthesis of drugs and natural products.
亚砜类化合物是一类应用广泛的中间体,在精细化工、医药、农药等有机合成中具有非常重要的作用和广泛的用途。
5) Thionyl chloride
氯化亚砜
1.
A new technology of continuous preparing phosphorus oxychloride and thionyl chloride;
连续联合制备氯化亚砜和三氯氧磷新工艺
2.
Production, application and market of thionyl chloride;
氯化亚砜的生产、应用及市场
6) chiral sulfoxides
手性亚砜
1.
The applications and research advance of various synthetic methods of chiral sulfoxides,introduction of titanium-,vanadium-catalyzed enantioselective s.
手性亚砜及其衍生物广泛作为重要手性中间体和辅剂、手性配体和催化剂、手性药物。
2.
The preparation of chiral sulfoxides and their applications in organic synthesis are reviewed.
本文对手性亚砜的制备及其在不对称反应和天然产物合成中的应用进行了综述。
3.
Catalytic asymmetric oxidation of sulfides is the best method for synthesis of chiral sulfoxides with respect to atomic economy and practice.
第一部分 手性亚砜及其衍生物广泛作为重要手性中间体和辅剂、手性配体和催化剂、手性药物,例如Esomeprazole。
补充资料：四亚甲基亚砜
分子式：
CAS号：
性质：液体。沸点235～237℃，折射率1.522。密度1.158g/cm3。由1,4-二溴丁烷与硫化钠反应获四氢噻吩，后者经氧化即得。溶剂及有机合成试剂。
CAS号：
性质：液体。沸点235～237℃，折射率1.522。密度1.158g/cm3。由1,4-二溴丁烷与硫化钠反应获四氢噻吩，后者经氧化即得。溶剂及有机合成试剂。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条