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1)  electrochemical polymerization
电化学氧化聚合
1.
The polyaniline/poly(vinyl alcohol)conductive composite film is synthesized using HClO 4 as the dopant and oxidant in reaction system by electrochemical polymerization.
以高氯酸为掺杂剂用电化学氧化聚合法制备了聚苯胺 (PAn) /聚乙烯醇 (PVA)导电复合膜。
2.
The preparation of poly(diaminonaphthalene)(PDAN) by chemical oxidation polymerization and electrochemical polymerization is summarized.
综述了化学氧化聚合和电化学氧化聚合合成聚萘二胺的研究进展及聚萘二胺纳米材料的性能和应用。
2)  chemical oxidative polymerization
化学氧化聚合
1.
The chemical oxidative polymerization of N-ethylaniline(EA) was carried in aqueous 1.
0mol/L的HCl溶液中的化学氧化聚合进行了动力学的研究。
2.
The various chemical methods for preparation of polyaniline nanofibers were introduced and the formation and growth mechanisms of polyaniline nanofibers in the chemical oxidative polymerization pr.
本工作综述了通过化学途径合成聚苯胺纳米纤维的各种方法,分析了苯胺的化学氧化聚合过程中聚苯胺纳米纤维的形成和生长机理,指出了存在的问题和今后的发展方向。
3.
Nanostructural electroconductive poly(aniline-co-diphenylamine-4-sulfonate) (PANDPS) nanoparticles with good self-stability were synthesized by chemical oxidative polymerization of aniline(AN) with diphenylamine-4-sulfonate(DPS) in HCl aqueous medium without any external additive.
在无任何外加添加剂的情况下,于盐酸介质中,通过苯胺(AN)与二苯胺磺酸(DPS)的化学氧化聚合制备了纳米结构导电磺化苯胺共聚物(PANDPS)。
3)  chemical oxidation polymerization
化学氧化聚合
1.
This paper describes a unique process of chemical oxidation polymerization of polyaniline using manganese dioxide as the oxidizing agent in the aqueousmedia.
研究了以二氧化锰为氧化剂,苯胺(An)化学氧化聚合的新型反应。
2.
This paper describes a unique process of chemical oxidation polymerization of polyaniline using manganese dioxide as the oxidizing agent in the aqueous media.
 研究了以二氧化锰为氧化剂,苯胺(ANI)化学氧化聚合的新型反应。
4)  Chemical Oxidative Polymerization
化学氧化聚合法
5)  Electrochemical polymerization
电化学聚合
1.
Study on the electrochemical polymerization of urushiol and its coordination polymer of holmium;
电化学聚合漆酚及其钬配合物研究
2.
The electrochemical polymerization of aniline were carried out by using the cyclic voltmmetric method in the different protonic acid.
利用循环伏安方法在不同质子酸掺杂下电化学聚合苯胺,并以聚合电量随循环次数的变化测定苯胺电聚合的速率。
3.
Electrochemical polymerization of aniline on CNT-nano TiO_2 film electrode has been achieved in 0.
9V范围内实现苯胺在碳纳米管-纳米TiO2膜电极上的电化学聚合,得到翠绿色的聚苯胺膜,并用交流阻抗谱对复合膜的电化学性质进行了表征。
6)  electropolymerization
电化学聚合
1.
Studies on the Electropolymerizations on Metal Surfaces——I The Electropolymerization of Phenols in Alkaline Solutions on Metal Electrodes;
金属表面上的电化学聚合研究——Ⅰ碱性介质中苯酚在金属电极上的电化学聚合
2.
Cyclic voltammetry was used to study the process of electropolymerization.
以吡咯和二缩三乙二醇为原料合成了N取代吡咯衍生物单体——双-[2-吡咯(乙氧基)]乙烷,并用循环扫描伏安技术研究了该单体的电化学聚合过程。
3.
Chloro 2 formylvinyl)ferrocene (2) and [Ru(bpy)(vpy) 2](PF 6) 2 (1) (bpy=2,2′ bipyridine, vpy=4 vinylpyridine) were copolymerized through reductive electropolymerization in acetonitrile containing 0 1 mol·L -1 TBAH as supporting electrolyte The electropolymerization was conducted by cyclic voltammetry from 0 7 to -2 15 V vs.
利用与钌乙烯基吡啶配合物 [Ru(bpy) (vpy) 2 ](PF6 ) 2 (1) (bpy =2 ,2′ bipyridine ,vpy =4 vinylpyridine)的电化学共聚 ,加速了 1 氯 2 甲酰基乙烯基二茂铁 (CFVF) (2 )的电化学聚合速度 ,制备了具有Fc+ Fc和Ru3+ Ru2 + 电化学响应的 1~ 2共聚膜 。
补充资料:氧化聚合
分子式:
CAS号:

性质:含有活泼氢原子的化合物如苯酚、苯胺、乙炔和硫醇等,在氧存在下,由金属络合物催化脱氢生成加成聚合物的反应。氧化聚合在植物成分的生物合成过程中是一个重要的反应,如占木材成分20%~30%的木质素是由松柏醇经酶氧化聚合的生成物。

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