1) axial coordination reaction
轴向配位反应
1.
Study on the spectroscopic properties of axial coordination reaction of hydroxy Zn porphyrin
羟基锌卟啉轴向配位反应的光谱性质研究
2.
meso tetrakis ( o chloroacetylamidophenyl) porphyrin (1) and its zinc complex (2) were synthesized and characterized by means of spectrophotometer technique, the equilibrium constants of the axial coordination reaction were measured between complex 2 and a serious of imidazoles and the molecular recognition of imidazoles by receptor porphyrin 2 was studied.
用紫外 -可见光谱法测定了配合物 2与三种典型的咪唑类配体轴向配位反应的缔合常数 ,研究了其作为主体分子对咪唑类客体的分子识别 。
3.
The axial coordination reaction of new tailed tryptophane iron(Ⅲ) tetraphenylporphyrin [Fe(Trp-TPP)Cl] with imidazole in trichloromethane solvent was studied.
研究了新型尾式色氨酸四苯基卟啉铁 ( ) [Fe( Trp- TPP) ]Cl在三氯甲烷中与咪唑 ( Im)轴向配位反应。
2) axial coordination
轴向配位反应
1.
It was reported that the axial coordination of new type of taUed valine tetraphenylporphyrinatoiron (Ⅲ) chloride (Fe Lvalcl) reacts with imdazole (Im) in dichloromethane.
研究了二氯甲烷中咪唑（Im）与尾式缬氨酸卟啉铁（Ⅲ）（FeLval（C1））的轴向配位反应，用光度法测得了该反应的平衡常数（K）、标准摩尔焓变（△Hm0）和标准摩尔熵变（△Sm0）。
2.
A thermodynamic study is reported on the axial coordination of para monosubstituted glutamic acid tetraphenylporphyrinatoiron(Ⅲ) chloride (FeL Glu Cl) with imidazole (Im) in trichloromethane.
研究了三氯甲烷中咪唑（Ｉｍ）与氯代（对位单取代谷氨酸四苯基）卟啉铁（Ⅲ）（简记为ＦｅＬＧｌｕＣｌ）的轴向配位反应。
3.
A thermodynamic study is reported on the axial coordination of tailed phenylalanie tetraphenyl porphyrinatoiron(Ⅲ) with imidazole in dichloromethane.
研究了二氯甲烷中咪唑与尾式苯丙氨酸卟啉铁（Ⅲ）的轴向配位反应。
3) axial coordination
轴向配位
1.
Themodynamic properties of the axial coordination between metallo porphyrins and indole were investigated by UV-Vis method.
研究了配合物与吲哚客体的轴向配位热力学性质。
2.
The thermodynamic of the axial coordination between this compound and three pairs of amino acid esters were in.
对该化合物与3对氨基酸甲酯客体的轴向配位热力学性质作了研究,从热力学数据和圆二色光谱探讨了与不同客体配位能力的差异。
3.
The axial coordination of porphyrin-fullerene compounds also has been researched primarily.
按文献方法合成了共价键连卟啉-富勒烯化合物,通过荧光光谱和光伏效应测得它们的光化学和光电转换性能,并对卟啉-富勒烯化合物的轴向配位进行了初步探究。
4) Axial coordination reaction
轴配反应
1.
The axial coordination reactions of p-tetrabromotetraphenylporphyrin zinc coordination compound Zn(II)TPP(Br4) with imidazole and pyridine have been investigated.
研究了β-四溴四苯基卟啉锌配合物[Zn(Ⅱ)TPP(Br_4)]在CHCl_3中与咪唑、吡啶等含氮碱的轴配反应,测定了体系的电子光谱,利用平衡移动法求出轴配反应的配位数(n)及平衡常数(K)。
2.
The electric absorption spectra of axial coordination reactions of tailed phenylalanine tetraphenylporphyrinato cobalt(Ⅱ) Co[Phe-TPP]with imidazole(Im),2 Methyl imidazole(2 MeIm) and N Methylimidazole(N MeIm) have been studied.
钴卟啉能可逆地结合氧可作为血红蛋白的模拟化合物,因此,研究钴卟啉与含氮配体的轴配反应有重要意义[13]。
3.
Coordination number and equilibrium constants of axial coordination reaction were measured by visible spectra techniques.
有关取代四苯基卟啉金属配合物的合成和轴配反应热力学研究已有很多报道 ,但人们的研究尚处在对称且苯环上连有较小取代基的四苯基卟啉锌、钴、铁等模拟化合物的合成、结构表征及光谱和配位反应热力学的研究阶段 [2 -4 ]。
5) Coordination reaction
配位反应
1.
A novel technology about the integration of separation and coordination reaction of hesperidin with Cu2+ in ion-exchange chromatography(IEC) column was presented and performed in this paper.
提出并实现了橙皮苷分离及其与Cu2+配位反应一体化的新设想,并借助离子交换色谱、紫外可见光谱、X-射线衍射、傅立叶红外光谱和核磁共振等分析手段探讨其作用机理。
2.
The rate of the coordination reaction between divalent metal ions and murexide in a water-in-oil microemulsion was determined by spectrophotometric technique to study the transport of the metal ions entrapped in the organogel formed by cationic surfactant cetyltrimethylammoni.
以微乳液中二价金属离子与紫脲酸胺之间的配位反应为指示反应 ,采用分光光度技术 ,研究了金属离子在由阳离子表面活性剂十六烷基三甲基溴化胺构建的微乳凝胶中的传质问题 。
3.
Coordination reaction between H 2HAPP and metal ion Zn(Ⅱ) in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)=1∶1] solvent was studied by UV Vis spectroscopic method, which indicated 1∶1 complexing between H 2HAPP and Zn(II) ion occurred easily in such a homogeneous sys.
适合 H2 HAPP与金属离子配位反应动力学等研究的均。
6) coordinate reaction
配位反应
1.
The constant of action, activationenergy and some thermodynamic parameters on the coordinate reaction of letrabenzoporphine with Cu 2+ and Co 2+ were determimed by spectrometric methods.
用光度法测定了四苯骈卟啉与Cu2 + ,Co2 + 配位反应速率常数、活化能及热力学参数 。
2.
The rate constant, activation energy and some thermodynamic parameters on the coordinate reaction of bridged crowned porphyrin with Co2+ and Cu2+ were determined by spectrometric methods.
用光度法测定了桥链冠醚卟啉与Ｃｏ２＋、Ｃｕ２＋配位反应的速率常数、活化能及热力学参数。
3.
The effect of the structure of porphyrin on the coordinate reaction was disscussed and their Uv-Vis and fluorescence spectra were reported.
用光度法测定了３种取代四苯基卟啉与Ｃｏ２＋、Ｃｕ２＋配位反应的速率常数、活化能及热力学参数。
补充资料：异配位体配位化合物
分子式：
CAS号：
性质：又称异配位体配位化合物。中心离子同时与两种以上不同配体共存于配位内界所组成的单核或多核配位化合物。例如，三氯·氨合铂(II)酸钾和(2)铜(II)-吡啶(py)-水杨酸(sal)配位化合物。在溶液中混配配位化合物的形成是普遍现象。与单一型配位化合物比较，它加强了中心体的化学个性(如易满足高配位数、增强不稳价态稳定性、光学性质改变等)，也加强了配体的反应活性和协同萃取效应。在湿法冶金、电化学、分析化学、药物化学、环境化学、生物无机化学和材料化学等方面有着重要作用。
CAS号：
性质：又称异配位体配位化合物。中心离子同时与两种以上不同配体共存于配位内界所组成的单核或多核配位化合物。例如，三氯·氨合铂(II)酸钾和(2)铜(II)-吡啶(py)-水杨酸(sal)配位化合物。在溶液中混配配位化合物的形成是普遍现象。与单一型配位化合物比较，它加强了中心体的化学个性(如易满足高配位数、增强不稳价态稳定性、光学性质改变等)，也加强了配体的反应活性和协同萃取效应。在湿法冶金、电化学、分析化学、药物化学、环境化学、生物无机化学和材料化学等方面有着重要作用。
说明：补充资料仅用于学习参考，请勿用于其它任何用途。
参考词条