1) skeletal isomerization of olefin
烯烃骨架异构化
1.
The FT-IR and NH 3-TPD investigations showed that the strong acid sites of H-FER zeolite, which are beneficial to the skeletal isomerization of olefin, were mainly the Brnsted acid sites.
红外光谱及NH3 TPD等实验结果表明 ,两者的强酸位主要是对烯烃骨架异构化反应有贡献的Br nsted酸位 。
3) skeletal isomerization
骨架异构化
1.
The latest advances in the skeletal isomerization of n-amythene to i-amythene, including the reaction mechanism, the choice of catalysts, etc, were reviewed.
综述了正戊烯骨架异构化为异戊烯工艺的反应原理,催化剂的选择,生产条件及工艺现状作。
2.
The CoAPO-11 molecular sieve was prepared by the hydrothermal method and used to catalyze the skeletal isomerization of(1-hexene).
用水热法合成了CoAPO-11分子筛,并考察了温度和空速对分子筛上1-己烯骨架异构化反应的影响。
3.
MCM-49 molecular sieve with different Si/Al ratios was synthesized hydrothermally under static condition and dynamic condition (autoclave rotated at 60 r/min), and its catalytic performance for skeletal isomerization of 1-butene was studied.
采用动态和静态水热合成法合成了不同Si/Al比的MCM 4 9分子筛 ,并考察了合成分子筛对 1 丁烯骨架异构化反应的催化性能 。
4) double bound isomerization
烯烃双键异构化
1.
Their catalytic activity for 1-hexene double bound isomerization was investigated and their catalytic reaction conditions were optimized for double bound isomerization.
研究了它们在烯烃双键异构化反应中的催化作用,优化了这两种催化剂在1—己烯双键异构化反应中的反应条件。
6) skeletal isomerization
骨架异构
1.
The results showed that the oligomerization,cracking,skeletal isomerization and hydrogen transfer reaction of 1-heptene occurred on acid catalysts.
结果表明,庚烯-1在酸性催化剂上会发生齐聚、裂化、骨架异构和氢转移等反应;在较高转化率下,甚至会发生四聚反应。
2.
The principle of skeletal isomerization reaction of C_5 olefin, advances in research of catalyst, and the present situation of isomerization process were discussed and reviewed.
对C_5烯烃骨架异构化反应原理、催化剂的研究进展,以及异构化的工艺现状作了探讨和综述。
补充资料:顺-反式异构体(cistrans isomer),1,2,4异构体
分子式:
CAS号:
性质:又称顺-反式异构体(cistrans isomer),1,2,4异构体或1,2,6异构体(1,2,4 isomer;1,2,6 isomer)。八面体配位化合物中,六个配体分别为3个A(如图中Cl:A1,A2,A3)和3个B(如图中Py:B1,B2,B3)(图暂缺)。当三个相同的配体中的两个(如A1与A3或B1与B3)互为反式,第三个(如A2或B2)与这两个A1与A3或B1与B3)均为顺式,这样的排布的异构体即为经式异构体。
CAS号:
性质:又称顺-反式异构体(cistrans isomer),1,2,4异构体或1,2,6异构体(1,2,4 isomer;1,2,6 isomer)。八面体配位化合物中,六个配体分别为3个A(如图中Cl:A1,A2,A3)和3个B(如图中Py:B1,B2,B3)(图暂缺)。当三个相同的配体中的两个(如A1与A3或B1与B3)互为反式,第三个(如A2或B2)与这两个A1与A3或B1与B3)均为顺式,这样的排布的异构体即为经式异构体。
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参考词条